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Pb(Zn1/3Nb2/3)(0.20)(Zr0.47Ti0.53)(0.80)O-3 ceramics, with the addition of 0-1.0wt% MnO2, were prepared by conventional mixed-oxide technique in a wide sintering temperature region from 1050 to 1200 degrees C. Microstructural and compositional analyses of these specimens have been carried out using X-ray diffraction (XRD) and scanning electron microscope (SEM). The effects of MnO2 dopants and the sintering temperature on the piezoelectric and dielectric properties of Pb(Zn1/3Nb2/3)(0.20)(Zr0.47Ti0.53)(0.80)O-3 ceramics have been investigated. Compared to higher densified temperature of 1200 degrees C for undoped specimen, the specimens with the MnO2 doping content above 0.2wt% have maximum density at 1100 degrees C sintering temperature. Simultaneously, the optimum piezoelectric properties were also obtained at 1100 degrees C for Mn-modified specimens. The values of electromechanical coupling factor, k(p) and dielectric loss, tan 8 were optimized for 0.5 wt% MnO2 doped specimen (k(p) = 0.65, tan delta = 0.2%), while the mechanical quality factor, Q(m) was maximized for 1.0 wt% MnO2 doped samples (Q. = 1300). In other words, the optimum sintering condition was found. (c) 2005 Elsevier B.V. All rights reserved.
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