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The effects of substrate-placing manner, deposition temperature and solution concentration on the preparation of ZnO films by chemical bath deposition were investigated in this work. The structures and the morphologies of as-deposited ZnO films were characterized by X-ray diffraction and scanning electron microscope, respectively. The results show that compared with vertically insertion, floating the substrates on the solutions could greatly improve the c-axis orientation of the films. The growth of ZnO films with orientation would also be favored at lower precursor concentrations and temperatures. When the concentration of Zn(CH3COO)(2)center dot 2H(2)O is 0.033 M/L and the deposited temperature is 60 degrees C, ZnO films which are well crystallized and highly c-axis orientated were obtained.
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