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作者:

Miao, Shaoshuai (Miao, Shaoshuai.) | Yang, Qianqian (Yang, Qianqian.) | Ai, Xicheng (Ai, Xicheng.) | Yang, Kaihua (Yang, Kaihua.) | Deng, Jinxiang (Deng, Jinxiang.) (学者:邓金祥) | Guo, Yanru (Guo, Yanru.) | Yuan, Shuai (Yuan, Shuai.) | Zhang, Hao (Zhang, Hao.)

收录:

EI SCIE

摘要:

In recent years, perovskite solar cells with low cost and high efficiency are developing rapidly. In view of the potential commercialization of perovskite solar cells, it is very important to upgrade its functional layer. ZnSnO (ZTO) has the advantages of high transmittance, so it is often used as the electron transport layer of solar cells. Oxygen vacancies in ZTO not only plays the role of carrier, but also is the main defect in ZTO. So we study the impact of oxygen vacancies in ZTO to solar cells by preparing ZTO solar cells with different Si doping concentrations. In this work, the amorphous metal oxide films Si-ZnSnO (SZTO) with different Si concentrations were prepared by RF magnetron sputtering. The XPS results indicate that the oxygen vacancies density in SZTO can be significantly reduced by Si doping. The carrier dynamics studies found that the electronic extraction and transfer ability of perovskite solar cell can be also improved with the reduction of oxygen vacancies in SZTO. With an improved electron transfer layer, the perovskite solar cell has a maximum photoelectric conversion efficiency of 13.4%, an open circuit voltage of 1.04 V and a short circuit current of 21.6 mAcm(-2). Filling factor is 0.67. (C) 2020 Elsevier B.V. All rights reserved.

关键词:

Oxygen vacancies Perovskite solar cells RF magnetron Sputtering ZnSnO

作者机构:

  • [ 1 ] [Miao, Shaoshuai]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Yang, Qianqian]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Yang, Kaihua]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Deng, Jinxiang]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Hao]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Ai, Xicheng]Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
  • [ 7 ] [Guo, Yanru]Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
  • [ 8 ] [Yuan, Shuai]Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

通讯作者信息:

  • [Yang, Qianqian]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

年份: 2020

卷: 835

6 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:37

JCR分区:1

被引次数:

WoS核心集被引频次: 12

SCOPUS被引频次: 11

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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