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Author:

He, B (He, B.) | Chen, GH (Chen, GH.) | Zhu, XH (Zhu, XH.) | Zhang, WL (Zhang, WL.) | Ding, Y (Ding, Y.) | Ma, ZJ (Ma, ZJ.) | Gao, ZH (Gao, ZH.) | Song, XM (Song, XM.) | Deng, JX (Deng, JX.) (Scholars:邓金祥)

Indexed by:

EI Scopus SCIE CSCD

Abstract:

Intrinsic hydrogenated microcrystalline silicon (mu c-Si:H) films have been prepared by hot-wire-assisted microwave electron-cyclotron-resonance chemical vapour deposition (HW-MWECR-CVD) under different deposition conditions. Fourier-transform infrared spectra and Raman spectra were measured. Optical band gap was determined by Tauc plots, and experiments of photo-induced degradation were performed. It was observed that hydrogen dilution plays a more essential role than substrate temperature in microcrystalline transformation at low temperatures. Crystalline volume fraction and mean grain size in the films increase with the dilution ratio (R=H-2/(H-2+SiH4)). With the rise of crystallinity in the films, the optical band gap tends to become narrower while the hydrogen content and photo-induced degradation decrease dramatically. The samples, were identified as mu c-Si:H films, by calculating the optical band gap. It is considered that hydrogen dilution has an effect on reducing the crystallization activation energy of the material, which promotes the heterogeneous solid-state phase transition characterized by the Johnson-Mehl-Avrami (JMA) equation. The films with the needed structure can be prepared by balancing deposition and crystallization through controlling process parameters.

Keyword:

hydrogen dilution HW-MWECR-CVD heterogeneous solid-state phase transition mu c-Si : H

Author Community:

  • [ 1 ] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 2 ] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
  • [ 3 ] Beijing Univ Technol, Coll Appl Sci, Beijing 100022, Peoples R China

Reprint Author's Address:

  • [He, B]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China

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Source :

CHINESE PHYSICS

ISSN: 1009-1963

Year: 2006

Issue: 4

Volume: 15

Page: 866-871

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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