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作者:

He, B (He, B.) | Chen, GH (Chen, GH.) | Zhu, XH (Zhu, XH.) | Zhang, WL (Zhang, WL.) | Ding, Y (Ding, Y.) | Ma, ZJ (Ma, ZJ.) | Gao, ZH (Gao, ZH.) | Song, XM (Song, XM.) | Deng, JX (Deng, JX.) (学者:邓金祥)

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EI Scopus SCIE CSCD

摘要:

Intrinsic hydrogenated microcrystalline silicon (mu c-Si:H) films have been prepared by hot-wire-assisted microwave electron-cyclotron-resonance chemical vapour deposition (HW-MWECR-CVD) under different deposition conditions. Fourier-transform infrared spectra and Raman spectra were measured. Optical band gap was determined by Tauc plots, and experiments of photo-induced degradation were performed. It was observed that hydrogen dilution plays a more essential role than substrate temperature in microcrystalline transformation at low temperatures. Crystalline volume fraction and mean grain size in the films increase with the dilution ratio (R=H-2/(H-2+SiH4)). With the rise of crystallinity in the films, the optical band gap tends to become narrower while the hydrogen content and photo-induced degradation decrease dramatically. The samples, were identified as mu c-Si:H films, by calculating the optical band gap. It is considered that hydrogen dilution has an effect on reducing the crystallization activation energy of the material, which promotes the heterogeneous solid-state phase transition characterized by the Johnson-Mehl-Avrami (JMA) equation. The films with the needed structure can be prepared by balancing deposition and crystallization through controlling process parameters.

关键词:

heterogeneous solid-state phase transition HW-MWECR-CVD hydrogen dilution mu c-Si : H

作者机构:

  • [ 1 ] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China
  • [ 2 ] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
  • [ 3 ] Beijing Univ Technol, Coll Appl Sci, Beijing 100022, Peoples R China

通讯作者信息:

  • [He, B]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100022, Peoples R China

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来源 :

CHINESE PHYSICS

ISSN: 1009-1963

年份: 2006

期: 4

卷: 15

页码: 866-871

JCR分区:2

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WoS核心集被引频次: 5

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