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摘要:
Preparation of homogeneous Ca3-xLaxCo4O9 (x = 0 similar to 0.4) single-phase ceramic powders was described using a tartrate complex method. The results show Ca3Co(4)O(9) phase can be obtained by calcining the dry gel at 750 degrees C for 5 h. The Ca3-xLaxCo4O9 ceramics have been prepared by spark plasma sintering at 800 degrees C for 5 min. Spark plasma sintering process is effective in synthesis of Ca3-xLaxCo4O9 compact ceramics. The thermal conductivity of Ca3-xLaxCo4O9 bulks was investigated from room temperature to 700 degrees C. The results show that Ca2.7La0.3Co4O9 has lowest thermal conductivity due to the increasing of phonon scattering by La substitution.
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来源 :
JOURNAL OF RARE EARTHS
ISSN: 1002-0721
年份: 2005
卷: 23
页码: 160-163
4 . 9 0 0
JCR@2022
ESI学科: CHEMISTRY;
JCR分区:4