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摘要:
WO3 and carbon mixed powder can be in-sit synthesized to compact WC bulk by spark plasma sintering. The phase, the density and the microstructure of the. sample synthesized at different temperatures have been studied. The mechanism of synthesis was analyzed. With the rising of the synthesis temperatures, WO3 can be rapidly reduced to WO2.72, WO2 and W, then carbonized to W2C and WC. Each step of the synthesis was overlapped. When the temperature was lower than 1118 degrees C, it is occur phase changes, but the density does not change significantly. When the temperature was higher than 1118 degrees C, a small amount of the remained W2C disappears, the sample begins to sinter, the density of the bulk is near the theoretical density. The microstructure of the sample changes with the synthesis temperatures. WO2.72 was rod shape, whereas WO3, WO2, W, W2C, WC were granular. The particle sizes grow from 0.2 mu m to about 0.5 mu m. CO2 gives off in the earlier stage Of WO3 reducing, CO gives off in the later stage during SPS synthesis. WO2.9 does not appear during the reducing reaction.
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来源 :
RARE METAL MATERIALS AND ENGINEERING
ISSN: 1002-185X
年份: 2005
期: 11
卷: 34
页码: 1743-1746
0 . 7 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
JCR分区:2
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