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作者:

Yue, M (Yue, M.) (学者:岳明) | Zhang, JX (Zhang, JX.) | Liu, WQ (Liu, WQ.) (学者:刘卫强) | Wang, GP (Wang, GP.)

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摘要:

The chemical stability of spark plasma sintering (SPS) anisotropic Nd-Fe-B magnets as well as the conventional sintered magnets in different electrolytes was studied by means of anodic potentiodynamic polarization experiments. In an alkaline solution, both magnets exhibit evident passive behavior, indicating that they possess good corrosion resistance in such an environment. In saline and weak acid solutions, however, no passivation occurred and SPS Nd-Fe-B has displayed a more positive corrosion potential E-corr and a lower corrosion current density I-corr, than that of the conventional sintered Nd-Fe-B with same composition. Then, electrochemical impedance spectroscopy (EIS) tests were carried out to investigate their corrosion kinetics in different solutions. According to Nyquist and Bode diagrams, a convenient equivalent circuit was modeled and the values of the proposed equivalent circuit components were calculated. It was found from the EIS plot formats that the electrochemical reaction of SPS Nd-Fe-B magnets was controlled by the step of surface charge transfer, i.e., activation polarization in alkaline solution, while controlled by the step of active substances adsorption on the magnet surface in saline and acidic solutions. Compared with conventional sintered Nd-Fe-B magnets, SPS Nd-Fe-B magnets possess better chemical stability in saline and weak acidic environment.

关键词:

chemical stability corrosion kinetics electrochemical reaction Nd-Fe-B magnets spark plasma sintering

作者机构:

  • [ 1 ] Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100022, Peoples R China
  • [ 2 ] Beijing Univ Technol, Inst Funct Mat, Sch Mat Sci & Engn, Beijing 100022, Peoples R China

通讯作者信息:

  • 岳明

    [Yue, M]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100022, Peoples R China

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来源 :

IEEE TRANSACTIONS ON MAGNETICS

ISSN: 0018-9464

年份: 2005

期: 10

卷: 41

页码: 3892-3894

2 . 1 0 0

JCR@2022

ESI学科: PHYSICS;

JCR分区:2

被引次数:

WoS核心集被引频次: 9

SCOPUS被引频次: 9

ESI高被引论文在榜: 0 展开所有

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