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The single phase p-type filled skutterudite CemLanFeCO3.0Sb12 compounds, where voids were filled by double elements, were synthesized by Spark plasma sintering (SPS) using powders of Co, Sb, Fe and rare earth Ce, La as starting materials. The thermoelectric properties of them were also studied. The results indicated that the electrical conductivity of CemLanFeCO3.Sb-0(12) compounds decreased with Ce and La filling fraction. The electrical conductivity decreases with the filling fraction of the Ce and La, while the lattice constant and the Seebeck coefficient of the compounds increase with the filling fraction of the Ce and La. Compared with the same filling fraction, the lattice thermal conductivity of CemLanFeCo3.0Sb12 is found to be smaller than that of Ce. FeCo3.0Sb12 and LanFeCo3.0Sb12. The compounds with m + n = 0.3 had a minimum value of thermal conductivity in this invertigation, indicating that when the Sb voids in the skutterudite structure were filled by Ce and La the coupling rattling and the irregular distribution between the two filler ions that give rise to the mass change of atom lead to the additional phonon scattering produced by lattice aberration. The compound Ce0.1La0.2FeCo3.0Sb12 has the dimensionless figure of merit ZT = 0.60 at 800 K.
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