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作者:

Wang, JS (Wang, JS.) (学者:王金淑) | Shu, Y (Shu, Y.) | Zhang, QW (Zhang, QW.) | Saito, F (Saito, F.) | Sato, T (Sato, T.)

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CPCI-S SCIE

摘要:

Mechanochemical reaction method was used for preparing fluorine-doped SrTiO3 and the influences of several parameters on the visible light photocatalysis of the samples were studied. In the samples of 5 mol% SrF2-SrTiO3 ground for 10-240 min, the sample ground for 60 min showed the highest capability for the elimination of NO. The postgrinding heat treatment at appropriate temperature (150-200degreesC) in air could improve the photo-oxidation capability of fluorine-doped SrTiO3 probably due to the decrease in the number of hydroxyl groups on the surface of the powder in the sample. The samples made by 1 - 5 mol% SrF2 - SrTiO3 mixtures showed high photocatalytic activity, whereas excess content of SrF2 resulted in decreasing activity due to the formation of a new fluoride compound in the sample. The sample prepared by grinding the mixture of 5 mol% SrF2 and 95 mol% SrTiO3 for I h followed by heat treatment at 150degreesC for 2 h showed about three and two times larger photocatalytic activity for the elimination of NO under the irradiation of visible light (wavelength > 510 nm) than pure SrTiO3 and P-25, respectively. (C) 2004 Elsevier B.V. All rights reserved.

关键词:

fluorine doping mechanochemical reaction photocatalysis SrTiO3 visible light range

作者机构:

  • [ 1 ] Tohoku Univ, Div Adv Syst, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
  • [ 2 ] Beijing Univ Technol, Sch Mat Sci & Engn, Beijing 100022, Peoples R China

通讯作者信息:

  • 王金淑

    [Wang, JS]Tohoku Univ, Div Adv Syst, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan

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来源 :

SOLID STATE IONICS

ISSN: 0167-2738

年份: 2004

期: 1-4

卷: 172

页码: 191-195

3 . 2 0 0

JCR@2022

ESI学科: PHYSICS;

JCR分区:2

被引次数:

WoS核心集被引频次: 44

SCOPUS被引频次: 47

ESI高被引论文在榜: 0 展开所有

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