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作者:

Hou, YD (Hou, YD.) (学者:侯育冬) | Zhu, MK (Zhu, MK.) | Wang, H (Wang, H.) | Wang, B (Wang, B.) (学者:王波) | Yan, H (Yan, H.) | Tian, CS (Tian, CS.)

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EI Scopus SCIE

摘要:

Low temperature sintering of 0.5 wt.% MnO2-added Pb((Zn1/3Nb2/3)(0.20) (Zr0.50Ti0.50)(0.80))O-3 ceramics (PZNT) was investigated using CuO as sintering aids. It was found that the addition of CuO significantly improved the sinterability of PZNT ceramics, resulting in a reduction of sintering temperature from 1050 to 900 degreesC. The CuO addition also influences in a pronounced way both the crystal structure and microstructure of the low temperature sintered PZNT materials. The materials are transformed from the tetragonal to the rhombohedral structure, and the grain sizes are decreased when CuO are added. The distortion of crystal structure for PZNT samples with CuO addition can be explained with Jahn-Teller effect for electron state d(9) Of Cu2+ ion. On the other hand, with the increasing of CuO addition, k(p), d(33) were slightly decreased, but Q(m) and tan delta were optimized at 1.5 wt.% CuO. (C) 2004 Elsevier B.V. All rights reserved.

关键词:

CuO additive Jahn-Teller effect low temperature sintering piezoelectric properties PZN-PZT

作者机构:

  • [ 1 ] Beijing Univ Technol, China Educ Minist, Key Lab Adv Funct Mat, Beijing 100022, Peoples R China
  • [ 2 ] Northwestern Polytech Univ, Dept Mat Sci & Engn, Xian 710072, Peoples R China

通讯作者信息:

  • 侯育冬

    [Hou, YD]Beijing Univ Technol, China Educ Minist, Key Lab Adv Funct Mat, Beijing 100022, Peoples R China

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来源 :

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY

ISSN: 0921-5107

年份: 2004

期: 1

卷: 110

页码: 27-31

3 . 6 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

JCR分区:2

被引次数:

WoS核心集被引频次: 33

SCOPUS被引频次: 37

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