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Author:

Zhou, Kai Ling (Zhou, Kai Ling.) | Wang, Changhao (Wang, Changhao.) | Wang, Zelin (Wang, Zelin.) | Han, Chang Bao (Han, Chang Bao.) | Zhang, Qianqian (Zhang, Qianqian.) | Ke, Xiaoxing (Ke, Xiaoxing.) | Liu, Jingbing (Liu, Jingbing.) | Wang, Hao (Wang, Hao.)

Indexed by:

EI Scopus SCIE

Abstract:

Single-atom catalysts (SACs) have exhibited extraordinary catalytic performance due to the utmost atom utilization efficiency and unique electronic statesviametal-support interactions. Rationally designing SACs at the atomic level by structural engineering is desirable for an efficient hydrogen evolution reaction (HER). Herein, single-atom Pt was anchored on two-dimensional (2D) Co(OH)(2)nanosheets growing on Ag nanowires (Pt-SA-Co(OH)(2)@Ag NW) to construct a seamlessly conductive network hybrid catalystviaelectrochemical phase transformation from metallic Co@Ag NW. The Ag NW network provides a continuous electron transport pathway through metal active sites, contributing to an extremely low charge transfer resistance (R-ct, 0.7 omega), and the hierarchical nanostructure has a large electrochemical surface area for high atom utilization efficiency and rich mass transport pathways for hydrogen generation and release. Moreover, Co(OH)(2)tailored Pt sites induce a local tip-enhancement electric field region around the Pt site and more d contribution for boosting H adsorption and H2O adsorption. Thus, the synthesized Pt-SA-Co(OH)(2)@Ag NW catalyst shows outstanding HER activity with only 29 mV overpotential in 1.0 M KOH at 10 mA cm(-2)and 22.5-fold higher mass activity than the commercial Pt/C catalyst.

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Author Community:

  • [ 1 ] [Zhou, Kai Ling]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Changhao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Han, Chang Bao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Qianqian]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Jingbing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Zelin]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China
  • [ 8 ] [Ke, Xiaoxing]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Wang, Changhao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Han, Chang Bao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

ENERGY & ENVIRONMENTAL SCIENCE

ISSN: 1754-5692

Year: 2020

Issue: 9

Volume: 13

Page: 3082-3092

3 2 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:139

Cited Count:

WoS CC Cited Count: 144

SCOPUS Cited Count: 146

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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