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作者:

Wang, Kuan (Wang, Kuan.) | Yan, Pengfei (Yan, Pengfei.) (学者:闫鹏飞) | Wang, Zelin (Wang, Zelin.) | Fu, Junjie (Fu, Junjie.) | Zhang, Zhenlu (Zhang, Zhenlu.) | Ke, Xiaoxing (Ke, Xiaoxing.) | Sui, Manling (Sui, Manling.) (学者:隋曼龄)

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EI Scopus SCIE

摘要:

Uniform doping has been recognized as an effective approach to improve the cycling performance of many layered cathodes. Herein, we propose non-uniform doping as a more effective approach to enhance the cycling stability of layered cathodesviathe precipitation strengthening mechanism. In this work, we investigate four doped (Cu, Ti, Mg, and Zn) P2-layered cathodes for sodium ion batteries and validate that cycling induced dopant segregation can substantially enhance the cyclability due to mitigation of bulk cracking. Our comprehensive analysis indicates that dopant evolution is quite diverse during electrochemical cycling, not only depending on the nature of each dopant but also the cycling conditions applied. The migration and segregation behaviors of inactive dopants demonstrate the complex dynamics within grain bulk during battery cycling, which also offers us chances to engineer the physicochemical properties of layered cathodes. Non-uniform doping opens a new avenue for designing battery materials with superior mechanical properties.

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作者机构:

  • [ 1 ] [Wang, Kuan]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Yan, Pengfei]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Zelin]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Fu, Junjie]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Ke, Xiaoxing]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Sui, Manling]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Zhenlu]Beijing Univ Posts & Telecommun, Sch Sci, Beijing 100876, Peoples R China

通讯作者信息:

  • 闫鹏飞 隋曼龄

    [Yan, Pengfei]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China;;[Sui, Manling]Beijing Univ Technol, Beijing Key Lab Microstruct & Property Solids, Fac Mat & Mfg, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF MATERIALS CHEMISTRY A

ISSN: 2050-7488

年份: 2020

期: 32

卷: 8

页码: 16690-16697

1 1 . 9 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:169

被引次数:

WoS核心集被引频次: 18

SCOPUS被引频次:

ESI高被引论文在榜: 0 展开所有

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