收录:
摘要:
Designing a simple method to prepare a binder- and carbon-free catalyst with a highly efficient and stable hydrogen evolution electro-catalytic performance in the alkaline media is necessary and urgent. Herein, we develop a low-temperature hydrothermal nitridation and crystal transformation process for the preparation of nitrogen-doped Ni(OH)(2)nanobelts decorated on 3D Ni foam (N-Ni(OH)(2)/NF), where the precursor of amorphous Ni(OH)(2)/3D Ni foam is fabricated by a simple electrodeposition process. The hydrogen evolution process of our N-Ni(OH)(2)/NF electrode is studied by using a classical three-electrode electrochemical measurement in the alkaline media. The as-prepared N-Ni(OH)(2)/NF electrode exhibits a small onset overpotential of 178 mV at 100 mA center dot cm(-2) along with the superior electro-catalytic durability and stability after 10,000 cycles and 24-h continuous operation. The good electrocatalytic hydrogen evolution performance of the N-Ni(OH)(2)/NF electrode may be attributed to the absence of inactive materials (conducting carbon and binder), the high electrochemical active sites with a double-layer capacitance (C-dl) of 9.33 mF center dot cm(-2), the doping effect of nitrogen atom into Ni(OH)(2)crystalline, and the crystal transformation of Ni(OH)(2). More importantly, this strategy may be used to modify other transition metal oxides/hydroxides/sulfides/phosphides/selenides for the improved electrocatalytic hydrogen evolution performance.
关键词:
通讯作者信息:
电子邮件地址: