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作者:

Zeng, ChuiTao (Zeng, ChuiTao.) | Zhou, KaiLing (Zhou, KaiLing.) | Jin, YuHong (Jin, YuHong.) | Zhang, QianQian (Zhang, QianQian.) | Liu, JingBing (Liu, JingBing.) | Wang, Hao (Wang, Hao.) (学者:汪浩)

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摘要:

Designing a simple method to prepare a binder- and carbon-free catalyst with a highly efficient and stable hydrogen evolution electro-catalytic performance in the alkaline media is necessary and urgent. Herein, we develop a low-temperature hydrothermal nitridation and crystal transformation process for the preparation of nitrogen-doped Ni(OH)(2)nanobelts decorated on 3D Ni foam (N-Ni(OH)(2)/NF), where the precursor of amorphous Ni(OH)(2)/3D Ni foam is fabricated by a simple electrodeposition process. The hydrogen evolution process of our N-Ni(OH)(2)/NF electrode is studied by using a classical three-electrode electrochemical measurement in the alkaline media. The as-prepared N-Ni(OH)(2)/NF electrode exhibits a small onset overpotential of 178 mV at 100 mA center dot cm(-2) along with the superior electro-catalytic durability and stability after 10,000 cycles and 24-h continuous operation. The good electrocatalytic hydrogen evolution performance of the N-Ni(OH)(2)/NF electrode may be attributed to the absence of inactive materials (conducting carbon and binder), the high electrochemical active sites with a double-layer capacitance (C-dl) of 9.33 mF center dot cm(-2), the doping effect of nitrogen atom into Ni(OH)(2)crystalline, and the crystal transformation of Ni(OH)(2). More importantly, this strategy may be used to modify other transition metal oxides/hydroxides/sulfides/phosphides/selenides for the improved electrocatalytic hydrogen evolution performance.

关键词:

Alkaline hydrogen evolution reaction Ni(OH)(2) Water splitting Nitrogen doped Electro-catalyst Nanostructured catalyst

作者机构:

  • [ 1 ] [Zeng, ChuiTao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhou, KaiLing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Jin, YuHong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, QianQian]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, JingBing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 汪浩

    [Jin, YuHong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China;;[Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF NANOPARTICLE RESEARCH

ISSN: 1388-0764

年份: 2020

期: 8

卷: 22

2 . 5 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:169

被引次数:

WoS核心集被引频次: 2

SCOPUS被引频次: 5

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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