In　this　scenario,　a　novel　spherical　like　SrWO(4)nanomaterial＇s　were　made　by　the　simple　co-precipitation　route　was　confirmed　by　various　characterisation　techniques.　The　Powder　X-Ray　diffraction　(P-XRD)　was　explained　the　crystalline　nature　of　the　as-prepared　materials;　the　obtained　diffraction　peaks　reveal　good　crystalline　nature　of　as　prepared　novel　SrWO(4)nanomaterials.　The　Williamson-Hall　(W-H)　plot　method　was　used　to　analyse　the　individual　role　of　particle　sizes　and　lattice　strain　on　the　peak　broadening　of　the　NPs　of　host　and　surfactant　doped　SrWO4.　The　morphology　of　the　host　SrWO(4)materials　has　been　spherical,　but　also　of　surfactants,　the　morphology　will　be　changed.　The　presenting　elements　and　the　oxidation　state　of　Sr,　O　and　W　were　confirmed　by　X-ray　Photoelectron　Spectroscopy　analysis.　Interestingly,　SrWO4.SDS+PVP　catalyst　having　an　efficient　activity　in　the　degradation　process　than　that　others　and　the　degradation　efficiency　95.7%　corresponds　to　methylene　blue　(MB)　degradation　within　90　mins.　In　Reactive　Oxidative　Species　study,　hydroxyl　and　superoxide　radical＇s　quenchers　are　the　main　reactive　species　in　the　MB　degradation　process.　On　the　other　hand,　the　recycling　test　has　confirmed　the　stability　and　reusability　of　the　catalysts.