Indexed by:
Abstract:
Three-dimensionally ordered mesoporous Mn2O3 (meso-Mn2O3) and its supported Au, Ru, and AuRu alloy (0.49 wt% Au/meso-Mn2O3, 0.48 wt% Ru/meso-Mn2O3, and 0.97 wt% AuRu/meso-Mn2O3 (Au/Ru molar ratio = 0.98)) nanocatalysts were prepared using the KIT-6-templating and polyvinyl alcohol-protected reduction methods, respectively. Physicochemical properties of the samples were characterized by means of numerous techniques, and their catalytic activities were evaluated for the combustion of methane. It is found that among all of the samples, 0.48 wt% Ru/meso-Mn2O3 and 0.97 wt% AuRu/meso-Mn2O3 performed the best (the reaction temperature (T-90%) at 90% methane conversion was 530-540 degrees C), but the latter showed a better thermal stability than the former. The partial deactivation of 0.97 wt% AuRu/meso-Mn2O3 due to H2O or CO2 introduction was reversible. It is concluded that the good catalytic activity and thermal stability of 0.97 wt% AuRu/meso-Mn2O3 wasassociated with the high dispersion of AuRu alloy NPs (2-5 nm) on the surface of meso-Mn2O3 and good low-temperature reducibility.
Keyword:
Reprint Author's Address:
Email:
Source :
INTERNATIONAL CONFERENCE ON COMPUTER INFORMATION AND AUTOMATION ENGINEERING
ISSN: 1757-8981
Year: 2018
Volume: 359
Language: English
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0