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NaNO3 and KNO3 are frequently-used molten salts as heat transfer media in solar energy applications. Experimental data of thermal conductivity for these salts and their mixtures from published literatures show large discrepancies, which lead to perplexity to the heat exchanger design in heat transfer process. In this paper, reliable data for NaNO3 and KNO3 are picked out based on the experimental method and apparatus and correlation. Then theoretical results of thermal conductivity for mixtures of NaNO3 and KNO3 are predicted with these correlations and a previously developed theoretical model. Comparison shows that theoretical correlations predict the thermal conductivity of NaNO3 and KNO3 with standard errors 1.77% and 2.97% respectively and that theoretical model predicts the thermal conductivity of NaNO3-KNO3 mixtures within standard error of 4.15%. Though the latter error includes contributions due to experiment and extrapolation of correlations for NaNO3 and KNO3 to the lower temperature range of measurement for their binary mixtures, the standard error 4.15% has been accurate enough. It is thus proved that correlations of NaNO3 and KNO3 and the method of predicting the thermal conductivity of their mixtures in the present work can be used for design of heat transfer system in solar energy applications. (C) 2017 The Authors. Published by Elsevier Ltd.
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