With　the　developing　of　wearable　electronics　and　information　society,　integrated　energy　storage　devices　are　urgently　demanded　to　be　integrated　on　flexible　substrates.　We　successfully　demonstrated　using　direct　laser-reduction　of　the　hydrated　GO　and　chloroauric　acid　(HAuCl4)　nanocomposite　to　fabricate　in-plane　micro-supercapacitors　(MSCs)　with　fast　ion　diffusion　on　paper.　The　electrode　conductivity　of　these　flexible　nanocomposites　reaches　up　to　1.1　x　10(6)　S　m(-1),　which　enhances　superior　rate　capability　of　micro-supercapacitors,　and　large　specific　capacitances　of　0.77　mF　cm(-2)　(17.2　F　cm(-3)　for　volumetric　capacitance)　at　1　V　s(-1),　and　0.46　mF　cm(-2)　(10.2　F　cm(-3))　at　100　V　s(-1).　We　also　have　demonstrated　that　pulsed　laser　irradiation　rapidly　converts　the　polyimide　(PI)　sheets　into　an　electrically　conductive　porous　carbon　structure　in　ambient　conditions.　The　specific　capacitance　of　single　layer　surface　supercapacitors　can　reach　20.4　mF/cm(2)　at　0.1　mA/cm(2)　discharge　current　density.　Furthermore,　we　successfully　fabricate　the　multi-layer　supercapacitor　with　the　PI　substrate　using　3D　femtosecond　laser　direct　writing,　and　the　specific　capacitances　of　three　layers　supercapacitors　is　37.5　mF/cm(2).