Organic　solvent　nanofiltration　(OSN)　is　an　emerging　membrane-based　technology　for　molecular　separation.　The　design　and　fabrication　of　membranes　with　unique　structures　are　important　to　obtain　high　performance.　Herein,　ZIF-8　nanoparticles　are　grown　in　situ　on　the　surface　of　graphene　oxide　(GO)　nanosheets　and　then　assembled　on　a　tubular　ceramic　substrate　through　a　vacuum-assisted　assembly　method.　ZIF-8　anchored　on　the　GO　nanosheets　is　evolved　into　ZnS　polyhedra　with　a　hollow　structure　through　in　situ　sulfurization.　The　formed　ZnS@GO　membrane　is　composed　of　a　layered　structure　of　GO　with　the　interlayer　intercalated　by　ZnS　hollow　polyhedra　and　demonstrates　high　permeance　for　organic　solvents.　Compared　to　that　of　the　ZIF-8@GO　membrane,　the　permeance　of　the　ZnS@GO　membrane　is　enhanced　by　4.4-fold　when　separating　dyes　from　methanol,　indicating　their　promising　potential　in　the　application　of　organic　solvent　nanofiltration.