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作者:

Teng, Weili (Teng, Weili.) | Zhou, Qinqin (Zhou, Qinqin.) | Wang, Xuekai (Wang, Xuekai.) | Che, Haibing (Che, Haibing.) | Hu, Peng (Hu, Peng.) | Li, Hongyi (Li, Hongyi.) (学者:李洪义) | Wang, Jinshu (Wang, Jinshu.) (学者:王金淑)

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EI Scopus SCIE

摘要:

Polypyrrole (PPy) based fiber-shaped supercapacitor (FSSC) is attracting increasing attention as energy storage devices of flexible and wearable electronic products in recent years. However, its application is limited by the low specific capacitance and poor rate capability, mainly suffering from inferior conductivity and inhibited ions channels of fiber electrode. Here, a high-performance flexible FSSC is constructed based on hierarchically interconnected porous poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS)/PPy composite fiber prepared by in situ chemical polymerization of pyrrole on a novel highly-conductive PEDOT:PSS hydrogel support. The good electronic and ionic conductor properties, hierarchically porous structure and p-p interaction of conducting polymer hybrid fiber ensure fast electrons transfer/ions diffusion and the efficient utilization of whole electrode. Benefiting from the well-designed hybrid architecture and synergistic effect, the PEDOT:PSS/PPy hybrid fiber in FSSC exhibits superb volumetric/areal/length specific capacitance (393.8 F cm(-3), 770.6 mF cm(-2) and 18.9 mF cm(-1) at 2.0 A cm(-3)) and excellent rate performance (52.8% capacitance retention even at ultrahigh current density of 50 A cm(-3)). The FSSC device displays record-high energy density (8.3 mWh cm(-3) or 16.2 mu Wh cm(-2) at such a high power density of 389.1 mW cm(-3) or 761.5 mu W cm(-2)) compared to other previously-reported PPy based FSSCs, as well as long-term cycle stability and exceptional flexibility. The outstanding electrochemical and flexural performances of our PPy based FSSC are competent for portable and wearable electronics.

关键词:

PEDOT:PSS Fiber-shaped supercapacitor Conducting polymer Polypyrrole High specific capacitance

作者机构:

  • [ 1 ] [Teng, Weili]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China
  • [ 2 ] [Zhou, Qinqin]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Xuekai]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China
  • [ 4 ] [Che, Haibing]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China
  • [ 5 ] [Hu, Peng]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China
  • [ 6 ] [Li, Hongyi]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China

通讯作者信息:

  • 王金淑

    [Zhou, Qinqin]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China;;[Wang, Jinshu]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat,Minist Educ, Beijing Int Sci & Technol Cooperat Base Carbon Ba, Beijing 100124, Peoples R China

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来源 :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

年份: 2020

卷: 390

1 5 . 1 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:115

被引次数:

WoS核心集被引频次: 70

SCOPUS被引频次: 81

ESI高被引论文在榜: 0 展开所有

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