Indexed by:
Abstract:
O3-layered metal oxides are promising cathode materials for high-energy Na-ion batteries (SIBs); however, they suffer from fast capacity fade. Here, we develop a high-performance O3-Na-Ni0.68Mn0.22Co0.10O2 cathode for SIBs toward practical applications by suppressing the formation of a rock salt layer at the cathode surface with an advanced electrolyte. The cathode can deliver a high specific capacity of similar to 196 mAh g(-1) and demonstrates >80% capacity retention over 1000 cycles. NaNi0.68Mn0.22Co0.10O2-hard carbon full-cells with practical loading (>2.5 mAh cm-2) and lean electrolyte (similar to 40 mu L) demonstrate similar to 82% capacity retention after 450 cycles. A 60 mAh single-layer pouch cell has also been fabricated and demonstrated stable performance. This work represents a significant leap in SIB development and brings new insights to the development of advanced layered metal oxide cathodes for alkaline-ion batteries.
Keyword:
Reprint Author's Address:
Source :
ACS ENERGY LETTERS
ISSN: 2380-8195
Year: 2020
Issue: 6
Volume: 5
Page: 1718-1725
2 2 . 0 0 0
JCR@2022
Cited Count:
WoS CC Cited Count: 91
SCOPUS Cited Count: 90
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4