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Author:

Niu Yuan (Niu Yuan.) | Cheng Shui-Yuan (Cheng Shui-Yuan.) (Scholars:程水源) | Ou Sheng-Ju (Ou Sheng-Ju.) | Yao Shi-Yin (Yao Shi-Yin.) | Shen Ze-Ya (Shen Ze-Ya.) | Guan Pan-Bo (Guan Pan-Bo.)

Indexed by:

PubMed

Abstract:

Ozone pollution in Handan has become severe in recent years and in the summer of 2018, the average maximum daily 8-hour average ozone concentration in Handan was 175 μg·m-3 with a maximum of 257 μg·m-3. Ozone concentrations exceeded the National Air Quality Grade Ⅱ Standard in 59% of cases. In this study, the H2O2/HNO3 indicator was applied to analyze summertime ozone sensitivity in Handan using the WRF-CMAQ modeling system. The results showed that H2O2/HNO3 was more appropriate than other ozone indicators, both theoretically and based on simulation outputs. The good simulation effect of CMAQ on H2O2 and HNO3 was attributed to fine emission inventory and grid resolution. The H2O2/HNO3 simulation results showed that the relative importance of a VOCs-limited regime decreased month by month; a VOCs-NO
x
-mixed-limited regime was dominant in June; and a NO
x
-limited regime was more dominant in July and August than in June. The remarkable spatial difference in VOCs and NO
x
 emission ratios among the counties of Handan led to differences in ozone sensitivity. The VOCs-limited regime was concentrated in counties where VOCs/NO
x
 emission ratios were lower than 1.7. Southern counties had a NO
x
-limited regime, where VOCs/NO
x
 emission ratios were higher than 6.9. Counties with VOCs/NO
x
 emission ratios varying from 1.7 to 6.9 were more susceptible to both VOCs and NO
x
. According to these results, the transition range of HCHO/NO2, O3/HNO3, and O3/NO
x
 ratios were adjusted to 0.35-0.6, 20-35, and 10-25 respectively. Adjusting the transition range of H2O2/(O3+NO2) was not effective, indicating that this indicator may not be applicable to Handan.

Keyword:

WRF-CMAQ photochemical indicator sensitivity ozone Handan City

Author Community:

  • [ 1 ] [Niu Yuan]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Cheng Shui-Yuan]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 3 ] [Ou Sheng-Ju]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 4 ] [Yao Shi-Yin]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 5 ] [Shen Ze-Ya]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 6 ] [Guan Pan-Bo]Key Laboratory of Beijing on Regional Air Pollution Control, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

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Source :

Huanjing kexue

ISSN: 0250-3301

Year: 2021

Issue: 6

Volume: 42

Page: 2691-2698

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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