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作者:

Dou, Yibo (Dou, Yibo.) | Zhou, Awu (Zhou, Awu.) | Yao, Yuechao (Yao, Yuechao.) | Lim, Sung Yul (Lim, Sung Yul.) | Li, Jian-Rong (Li, Jian-Rong.) (学者:李建荣) | Zhang, Wenjing (Zhang, Wenjing.)

收录:

EI SCIE

摘要:

The utilization of solar energy for CO2 reduction reaction (CO2RR) into valuable hydrocarbons offers attractive solution towards low-carbon future, but their performance is affected by the competing hydrogen evolution reaction (HER) that occurs simultaneously. Herein, we proposed maximizing interface integration and surface reconstructing engineer strategy to improve the CO2RR activity and selectivity of heterojunction photocatalyst. A surface-reconstructed ZnO/CuOx catalysts are uniformly anchored on the porous carbon nanosheet arrays that are supported by carbon nanofibers (ZnO/CuOx-C CNFs). Downsizing ZnO/CuOx maximizes the interface integration of components to promote electron-hole pairs separation and increase surface active site density. Moreover, the surface reconstruction (the formation of the hydroxyl groups on ZnO via facile light irradiation) promotes the kinetic of CO2RR to CH4 and oxygen evolution reaction (OER), while depressing the competing HER and CO generation. All these advantages contribute to the excellent catalytic performance: a high CH4 generation rate of 241.6 mu mol h(-1) g(-1) with the selectivity of similar to 96 % for ZnO/CuOx-C CNFs under full light irradiation. The insight into the modification of photocatalyst structure and mechanism investigation pave the way for a new design strategy to advance solar photocatalytic technology for CO2 reduction.

关键词:

Interface integration Photocatalytic CO2 reduction Surface reconstruction ZnO/CuOx heterojunction

作者机构:

  • [ 1 ] [Dou, Yibo]Tech Univ Denmark, Dept Environm Engn, Miljovej 113, DK-2800 Lyngby, Denmark
  • [ 2 ] [Yao, Yuechao]Tech Univ Denmark, Dept Environm Engn, Miljovej 113, DK-2800 Lyngby, Denmark
  • [ 3 ] [Zhang, Wenjing]Tech Univ Denmark, Dept Environm Engn, Miljovej 113, DK-2800 Lyngby, Denmark
  • [ 4 ] [Zhou, Awu]Beijing Univ Technol, Dept Environm Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Jian-Rong]Beijing Univ Technol, Dept Environm Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 6 ] [Lim, Sung Yul]Kyung Hee Univ, Dept Chem & Res Inst Basic Sci, Seoul 02447, South Korea
  • [ 7 ] [Zhou, Awu]Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

通讯作者信息:

  • 李建荣

    [Zhang, Wenjing]Tech Univ Denmark, Dept Environm Engn, Miljovej 113, DK-2800 Lyngby, Denmark;;[Li, Jian-Rong]Beijing Univ Technol, Dept Environm Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

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来源 :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

年份: 2021

卷: 286

2 2 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:7

被引次数:

WoS核心集被引频次: 45

SCOPUS被引频次: 45

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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