Two　novel　bis-(beta-diketonate)　ligands,　1,1　＇-(anthracene-1,8-diyl)bis(butane-1,3-dione)　(H2L1),　1,1　＇-(anthracene1,5-diyl)bis(4,4,4-trifluorobutane-1,3-dione)　(H2L2)　have　been　designed　and　synthesized　for　self-assembly　of　the　luminescent　supramolecular　coordination　compounds　with　transition　and　lanthanide　metals.　Two　neutral　dinuclear　supramolecular　assemblies　Cu(II)-bis-beta-diketonate　macrocyclic　complex　[Cu2(L1)2](CH3OH)2　(1.2CH3OH)　and　Eu(III)　bis-beta-diketonate　triple-stranded　complex　[Eu2(L2)3](CH3OH)4　(2.4CH3OH)　have　been　characterized　by　various　spectroscopic　techniques.　Their　photophysical　properties　were　further　investigated.　Xray　single　crystal　structural　analysis　revealed　that　complex　1.2CH3OH　adopts　a　1D　chain　arrangement　which　is　constructed　with　a　pitch　of　1.951　angstrom　through　intermolecular　hydrogen　bonds　along　the　b　axis.　The　slightly　distorted　parallelogram　of　1　is　a　neutral　[M2L2]-type　macrocycle　with　a　size　of　5.40　angstrom　x　8.40　angstrom.　The　triple-stranded　helicate　CPK　(Corey-Pauling-Koltun)　diagram　was　calculated　using　Scigress　2.6　program.