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Author:

Wang Chenchen (Wang Chenchen.) | Liu Luojia (Liu Luojia.) | Zhao Shuo (Zhao Shuo.) | Liu Yanchen (Liu Yanchen.) | Yang Yubo (Yang Yubo.) | Yu Haijun (Yu Haijun.) (Scholars:尉海军) | Lee Suwon (Lee Suwon.) | Lee Gi-Hyeok (Lee Gi-Hyeok.) | Kang Yong-Mook (Kang Yong-Mook.) | Liu Rong (Liu Rong.) | Li Fujun (Li Fujun.) | Chen Jun (Chen Jun.)

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Abstract:

Layered transition-metal oxides have attracted intensive interest for cathode materials of sodium-ion batteries. However, they are hindered by the limited capacity and inferior phase transition due to the gliding of transition-metal layers upon Na+ extraction and insertion in the cathode materials. Here, we report that the large-sized K+ is riveted in the prismatic Na+ sites of P2-Na0.612K0.056MnO2 to enable more thermodynamically favorable Na+ vacancies. The Mn-O bonds are reinforced to reduce phase transition during charge and discharge. 0.901 Na+ per formula are reversibly extracted and inserted, in which only the two-phase transition of P2 ↔ P'2 occurs at low voltages. It exhibits the highest specific capacity of 240.5 mAh g-1 and energy density of 654 Wh kg-1 based on the redox of Mn3+/Mn4+, and a capacity retention of 98.2% after 100 cycles. This investigation will shed lights on the tuneable chemical environments of transition-metal oxides for advanced cathode materials and promote the development of sodium-ion batteries.

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Author Community:

  • [ 1 ] [Wang Chenchen]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, China
  • [ 2 ] [Liu Luojia]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, China
  • [ 3 ] [Zhao Shuo]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, China
  • [ 4 ] [Liu Yanchen]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, China
  • [ 5 ] [Yang Yubo]College of Materials Science and Engineering, Beijing University of Technology, Beijing, China
  • [ 6 ] [Yu Haijun]College of Materials Science and Engineering, Beijing University of Technology, Beijing, China
  • [ 7 ] [Lee Suwon]Department of Materials Science and Engineering, Korea University, Seoul, Republic of Korea
  • [ 8 ] [Lee Gi-Hyeok]Department of Materials Science and Engineering, Dongguk University, Seoul, Republic of Korea
  • [ 9 ] [Kang Yong-Mook]Department of Materials Science and Engineering, Korea University, Seoul, Republic of Korea
  • [ 10 ] [Liu Rong]Secondary Ion Mass Spectrometry Facility, Western Sydney University, Locked 17 Bag 1797, Penrith, NSW, Australia
  • [ 11 ] [Li Fujun]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, China. fujunli@nankai.edu.cn
  • [ 12 ] [Chen Jun]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, China

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Source :

Nature communications

ISSN: 2041-1723

Year: 2021

Issue: 1

Volume: 12

Page: 2256

1 6 . 6 0 0

JCR@2022

ESI HC Threshold:169

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 337

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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