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Gold thin films have attracted a growing number attention because of their advantages such as easy preparation, conveniently subsequent modifications, good chemical stability, high electrical conductivity and low cytotoxicity. The preparation of continuous metal layer on capillary has become a classic leading step in the field of analytical chemistry. In recent years, researchers have established a variety of methods to prepare gold thin films, which has been applied in many fields. This paper reviews the preparation methods of gold thin films based on capillary, and its application in electrochemical sensing analysis, mainly discussing the technical characteristics and research status of electroless deposition, electrochemical deposition and physical vapor deposition. In addition, the development prospects of gold plating on capillary are also prospected.
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