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作者:

Chen, Wenwen (Chen, Wenwen.) | Liu, Zhongliang (Liu, Zhongliang.) (学者:刘中良) | Li, Yanxia (Li, Yanxia.) | Liao, Qiang (Liao, Qiang.) | Zhu, Xun (Zhu, Xun.)

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摘要:

Microbial fuel cells (MFCs) are a promising biotechnology that realizes the transformation of wastewater treatment from an energy consumption to an electricity generation process. However, the tedious process and the large resources consuming in preparing powder ORR catalysts are still non-negligible limiting factors for application. This study aims at proposing an energy-efficient method for preparing three-dimensional binder-free air cathode for MFCs: non-noble composite catalysts based on graphene and MnO2 are synthesized directly on stainless steel fiber felt (SSFF) by pre-fixing and electro-reducing graphene oxide on SSFF (rGO-SSFF), and then in-situ depositing MnO2 nanocatalysts on rGO-SSFF (rGO@MnO2-SSFF). The experimental results show that the ORR ability of rGO@MnO2-SSFF cathode is greater than that of Pt/C-CC cathode, even if the performance of rGO@MnO2 powder catalyst is slightly lower than that of the traditional Pt/C catalyst. The excellent performance is found to be due to the three-dimensional framework-pore structure of SSFF which helps the prepared cathode possess larger electrochemical active area (8415.18 m(2) m(-3)) than Pt/C-CC cathode (7518.13 m(2) m(-3)). The proposed method provides a new way to reduce the cost (labor, materials and energy) of air cathode while ensuring the high electricity output of MFCs. (C) 2021 Elsevier Ltd. All rights reserved.

关键词:

Stainless steel fiber felt Air cathode Microbial fuel cells Oxygen reduction activity Preparation optimization

作者机构:

  • [ 1 ] [Chen, Wenwen]Beijing Univ Technol, Dept New Energy Sci & Engn, MoE Key Lab Enhanced Heat Transfer & Energy Conse, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Zhongliang]Beijing Univ Technol, Dept New Energy Sci & Engn, MoE Key Lab Enhanced Heat Transfer & Energy Conse, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Yanxia]Beijing Univ Technol, Dept New Energy Sci & Engn, MoE Key Lab Enhanced Heat Transfer & Energy Conse, Beijing 100124, Peoples R China
  • [ 4 ] [Liao, Qiang]Chongqing Univ, MoE Key Lab Low Grade Energy Utilizat Technol & S, Chongqing 400030, Peoples R China
  • [ 5 ] [Zhu, Xun]Chongqing Univ, MoE Key Lab Low Grade Energy Utilizat Technol & S, Chongqing 400030, Peoples R China

通讯作者信息:

  • 刘中良

    [Liu, Zhongliang]Beijing Univ Technol, Dept New Energy Sci & Engn, MoE Key Lab Enhanced Heat Transfer & Energy Conse, Beijing 100124, Peoples R China

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来源 :

ENERGY

ISSN: 0360-5442

年份: 2021

卷: 222

9 . 0 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:87

JCR分区:1

被引次数:

WoS核心集被引频次: 13

SCOPUS被引频次: 19

ESI高被引论文在榜: 0 展开所有

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