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Author:

Wang, Chenchen (Wang, Chenchen.) | Liu, Luojia (Liu, Luojia.) | Zhao, Shuo (Zhao, Shuo.) | Liu, Yanchen (Liu, Yanchen.) | Yang, Yubo (Yang, Yubo.) | Yu, Haijun (Yu, Haijun.) | Lee, Suwon (Lee, Suwon.) | Lee, Gi-Hyeok (Lee, Gi-Hyeok.) | Kang, Yong-Mook (Kang, Yong-Mook.) | Liu, Rong (Liu, Rong.) | Li, Fujun (Li, Fujun.) | Chen, Jun (Chen, Jun.)

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Abstract:

Layered transition-metal oxides have attracted intensive interest for cathode materials of sodium-ion batteries. However, they are hindered by the limited capacity and inferior phase transition due to the gliding of transition-metal layers upon Na+ extraction and insertion in the cathode materials. Here, we report that the large-sized K+ is riveted in the prismatic Na+ sites of P2-Na0.612K0.056MnO2 to enable more thermodynamically favorable Na+ vacancies. The Mn-O bonds are reinforced to reduce phase transition during charge and discharge. 0.901 Na+ per formula are reversibly extracted and inserted, in which only the two-phase transition of P2 <-> P'2 occurs at low voltages. It exhibits the highest specific capacity of 240.5 mAh g(-1) and energy density of 654 Wh kg(-1) based on the redox of Mn3+/Mn4+, and a capacity retention of 98.2% after 100 cycles. This investigation will shed lights on the tuneable chemical environments of transition-metal oxides for advanced cathode materials and promote the development of sodium-ion batteries. High-capacity and structural stable cathode materials are challenges for sodium-ion batteries. Here, the authors report a layered P2-Na0.612K0.056MnO2 with large-sized K+ riveted in the Na-layers to enable 0.9 Na+ (de)insertion with a reversible phase transition of P2-P'2.

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Author Community:

  • [ 1 ] [Wang, Chenchen]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China
  • [ 2 ] [Liu, Luojia]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China
  • [ 3 ] [Zhao, Shuo]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China
  • [ 4 ] [Liu, Yanchen]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China
  • [ 5 ] [Li, Fujun]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China
  • [ 6 ] [Chen, Jun]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China
  • [ 7 ] [Yang, Yubo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing, Peoples R China
  • [ 8 ] [Yu, Haijun]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing, Peoples R China
  • [ 9 ] [Lee, Suwon]Korea Univ, Dept Mat Sci & Engn, Seoul, South Korea
  • [ 10 ] [Kang, Yong-Mook]Korea Univ, Dept Mat Sci & Engn, Seoul, South Korea
  • [ 11 ] [Lee, Gi-Hyeok]Dongguk Univ, Dept Mat Sci & Engn, Seoul, South Korea
  • [ 12 ] [Lee, Gi-Hyeok]Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA USA
  • [ 13 ] [Liu, Rong]Western Sydney Univ, Secondary Ion Mass Spectrometry Facil, Locked 17 Bag 1797, Penrith, NSW, Australia

Reprint Author's Address:

  • [Li, Fujun]Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr Recast, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin, Peoples R China

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Source :

NATURE COMMUNICATIONS

ISSN: 2041-1723

Year: 2021

Issue: 1

Volume: 12

1 6 . 6 0 0

JCR@2022

ESI Discipline: Multidisciplinary;

ESI HC Threshold:169

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 273

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 8 Unfold All

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WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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