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作者:

Hanif, Muhammad Bilal (Hanif, Muhammad Bilal.) | Gao, Jiu-Tao (Gao, Jiu-Tao.) | Qayyum, Sana (Qayyum, Sana.) | Shaheen, Kausar (Shaheen, Kausar.) | Wang, Yue-Peng (Wang, Yue-Peng.) | Yasir, Muhammad (Yasir, Muhammad.) | Li, Chang-Jiu (Li, Chang-Jiu.) | Li, Cheng-Xin (Li, Cheng-Xin.)

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EI Scopus SCIE

摘要:

The modified Pechini method was applied to prepare a highly active and novel cathode material La0.7Sr0.3Ti0.15Fe0.65Ni0.2O3-delta (LSTFN). This material was coated on the LGSM electrolyte through a screen-printing technique with variable thicknesses of 28 +/- 8, 41 +/- 8, and 62 +/- 8 mu m, respectively. Different fabrication parameters, including sintering temperature, time, coating thickness, and variations in ball-milling, which affect the electrochemical performance of the cathode material, were investigated. X-ray diffraction analysis of the cathode material suggested that it exhibits a cubic crystal structure with a LSTFN single phase. The morphological studies were conducted using scanning electron microscopy (SEM), which confirmed that the electrode material had a highly porous structure. Meanwhile, the electrochemical properties of the material were studied by electrochemical impedance spectroscopy (EIS), which revealed that by varying different parameters, the electrochemical performance of the electrode material was enhanced. The coated cathode materials with variable thicknesses were analyzed at different sintering temperatures and times. Experimental results suggest that the optimum sintering temperature and time were 950 degrees C and 3 h, respectively, at which LSTFN exhibits the minimum polarization resistance (R-P) of 0.046 Omega cm(2) when sintered at 800 degrees C for 3 h.

关键词:

La0.7Sr0.3Ti0.15Fe0.65Ni0.2O3-delta (LSTFN) Sintering-temperature Coating thickness Polarization resistance

作者机构:

  • [ 1 ] [Hanif, Muhammad Bilal]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 2 ] [Gao, Jiu-Tao]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 3 ] [Wang, Yue-Peng]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 4 ] [Li, Chang-Jiu]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 5 ] [Li, Cheng-Xin]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 6 ] [Shaheen, Kausar]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Shaheen, Kausar]Univ Peshawar, Jinnah Coll Women, Dept Phys, Peshwar 25120, Khyber Pakhtunk, Pakistan
  • [ 8 ] [Hanif, Muhammad Bilal]Inst Space & Technol, Dept Mat Sci & Engn, Islamabad 44000, Pakistan
  • [ 9 ] [Yasir, Muhammad]Inst Space & Technol, Dept Mat Sci & Engn, Islamabad 44000, Pakistan
  • [ 10 ] [Qayyum, Sana]Lahore Univ Management Sci LUMS, Dept Chem & Chem Engn, Lahore, Pakistan

通讯作者信息:

  • [Li, Cheng-Xin]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China

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来源 :

CERAMICS INTERNATIONAL

ISSN: 0272-8842

年份: 2021

期: 8

卷: 47

页码: 10893-10904

5 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:116

JCR分区:1

被引次数:

WoS核心集被引频次: 19

SCOPUS被引频次: 21

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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