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作者:

Zhang, Yiwei (Zhang, Yiwei.) | Liu, Fengjing (Liu, Fengjing.) | Jiang, Chao (Jiang, Chao.) | Tang, Fawei (Tang, Fawei.) | Zhang, Xinping (Zhang, Xinping.) (学者:张新平)

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摘要:

The robust material tunability of the hybrid organic-inorganic perovskite (HOIP) has attracted considerable research interests to explore the application in photoelectronic devices. Huge hysteresis has been recognised as a main problem in HOIP-based photoelectric devices; the origin of hysteresis has been attributed to the ion migration and trap states in HOIP materials. In this study, we designed and synthesised a HOIP single crystal with one-dimensional structure where the PbI42- octahedron is caged by the organic chains. The ion migration can be dramatically suppressed by the quantum size effect. Besides, in the single crystal trap states density is ultra-low due to the absence of grain boundaries. As a result, photodetectors based on this 1D HOIP single crystal show negligible hysteresis I-V curves. Moreover, a high quality ohmic contact is formed between electrodes and 1D HOIP, which is beneficial for photocarrier extraction. A responsivity of 80 mA W-1 and EQE of 30% are realised. The response speed is determined to be less than 0.4 ms. In addition, the photodetectors based on the novel 1D single crystal present good stability; after 3 months of ambient storage, 85% of its original photocurrent generation ability is retained.

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作者机构:

  • [ 1 ] [Zhang, Yiwei]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Xinping]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Fengjing]Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
  • [ 4 ] [Jiang, Chao]Natl Ctr Nanosci & Technol, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
  • [ 5 ] [Liu, Fengjing]Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China
  • [ 6 ] [Jiang, Chao]Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, Beijing 100190, Peoples R China
  • [ 7 ] [Tang, Fawei]Beijing Univ Technol, Coll Mat Sci & Engn, Educ Minist China, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China

通讯作者信息:

  • 张新平

    [Zhang, Xinping]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

年份: 2021

期: 10

卷: 9

页码: 3470-3476

6 . 4 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:116

JCR分区:1

被引次数:

WoS核心集被引频次: 3

SCOPUS被引频次: 3

ESI高被引论文在榜: 0 展开所有

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