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摘要:
The robust material tunability of the hybrid organic-inorganic perovskite (HOIP) has attracted considerable research interests to explore the application in photoelectronic devices. Huge hysteresis has been recognised as a main problem in HOIP-based photoelectric devices; the origin of hysteresis has been attributed to the ion migration and trap states in HOIP materials. In this study, we designed and synthesised a HOIP single crystal with one-dimensional structure where the PbI42- octahedron is caged by the organic chains. The ion migration can be dramatically suppressed by the quantum size effect. Besides, in the single crystal trap states density is ultra-low due to the absence of grain boundaries. As a result, photodetectors based on this 1D HOIP single crystal show negligible hysteresis I-V curves. Moreover, a high quality ohmic contact is formed between electrodes and 1D HOIP, which is beneficial for photocarrier extraction. A responsivity of 80 mA W-1 and EQE of 30% are realised. The response speed is determined to be less than 0.4 ms. In addition, the photodetectors based on the novel 1D single crystal present good stability; after 3 months of ambient storage, 85% of its original photocurrent generation ability is retained.
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来源 :
JOURNAL OF MATERIALS CHEMISTRY C
ISSN: 2050-7526
年份: 2021
期: 10
卷: 9
页码: 3470-3476
6 . 4 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:116
JCR分区:1