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作者:

Wei, Qiumei (Wei, Qiumei.) | Riaz, Adeel (Riaz, Adeel.) | Zhukov, Sergey (Zhukov, Sergey.) | Hofmann, Kathrin (Hofmann, Kathrin.) | Zhu, Mankang (Zhu, Mankang.) | Hou, Yudong (Hou, Yudong.) (学者:侯育冬) | Roedel, Jurgen (Roedel, Jurgen.) | Venkataraman, Lalitha Kodumudi (Venkataraman, Lalitha Kodumudi.)

收录:

EI SCIE

摘要:

Quenching alkaline bismuth titanates from sintering temperatures results in increased lattice distortion and consequently higher depolarization temperature. This work investigates the influence of quenching on the ergodicity of relaxor Na1/2Bi1/2TiO3-BaTiO3-K0.5Na0.5NbO3. A distinct departure from ergodicity is evidenced from the increase in remanent polarization and the absence of frequency dispersion in the permittivity response of poled samples. Further, the samples exhibit enhanced negative strain upon application of electric field, indicating proclivity towards correlated polar nanoregions, corroborated by the enhanced tetragonal distortion. As a result, ergodic relaxor Na1/2Bi1/2TiO3-6BaTiO(3)-3K(0.5)Na(0.5)NbO(3) exhibits a depolarization temperature of 85 degrees C with a 60% increase in remanent polarization and approximately a threefold increase in remanent strain upon quenching. Quenching-induced changes in the local environment of Na+ and Bi3+ cations hinder the development of ergodicity promoted by the A-site disorder. These results provide new insight into tailoring ergodicity of relaxor ferroelectrics.

关键词:

ferroelectricity ferroelectric materials free ceramics lead&#8208 relaxors

作者机构:

  • [ 1 ] [Wei, Qiumei]Tech Univ Darmstadt, Dept Mat & Earth Sci, Darmstadt, Germany
  • [ 2 ] [Riaz, Adeel]Tech Univ Darmstadt, Dept Mat & Earth Sci, Darmstadt, Germany
  • [ 3 ] [Zhukov, Sergey]Tech Univ Darmstadt, Dept Mat & Earth Sci, Darmstadt, Germany
  • [ 4 ] [Roedel, Jurgen]Tech Univ Darmstadt, Dept Mat & Earth Sci, Darmstadt, Germany
  • [ 5 ] [Venkataraman, Lalitha Kodumudi]Tech Univ Darmstadt, Dept Mat & Earth Sci, Darmstadt, Germany
  • [ 6 ] [Wei, Qiumei]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Coll Mat Sci & Engn,Fac Mat & Mfg, Beijing, Peoples R China
  • [ 7 ] [Zhu, Mankang]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Coll Mat Sci & Engn,Fac Mat & Mfg, Beijing, Peoples R China
  • [ 8 ] [Hou, Yudong]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Coll Mat Sci & Engn,Fac Mat & Mfg, Beijing, Peoples R China
  • [ 9 ] [Hofmann, Kathrin]Tech Univ Darmstadt, Eduard Zintl Inst Inorgan & Phys Chem, Darmstadt, Germany

通讯作者信息:

  • [Venkataraman, Lalitha Kodumudi]Tech Univ Darmstadt, Dept Mat & Earth Sci, Darmstadt, Germany

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来源 :

JOURNAL OF THE AMERICAN CERAMIC SOCIETY

ISSN: 0002-7820

年份: 2021

期: 7

卷: 104

页码: 3316-3324

3 . 9 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:8

被引次数:

WoS核心集被引频次: 14

SCOPUS被引频次: 14

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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