• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Lu, Yahua (Lu, Yahua.) | Qin, Zhenping (Qin, Zhenping.) | Wang, Naixin (Wang, Naixin.) (Scholars:王乃鑫) | An, Quan-Fu (An, Quan-Fu.) | Guo, Hongxia (Guo, Hongxia.)

Indexed by:

EI Scopus SCIE

Abstract:

Organic solvent nanofiltration is a promising separation technology for removing solute from an organic medium. However, the fabrication of organic solvent nanofiltration membranes with stable separation performance is still a challenge. Herein, a hydrophobic polyelectrolyte multilayer membrane was prepared through a layer-bylayer self-assembly and counterion exchange method. Poly(diallyl dimethyl ammonium chloride) (PDDA)/polyacrylic acid (PAA) multilayer was self-assembled on the surface of the hydrolyzed polyacrylonitrile substrate through electrostatic interaction. Simultaneously, calcium silicate hydrate (CSH) nanoparticles were in situ grown during the multilayer formation process due to the incorporation of precursor in polyelectrolyte solutions. Therefore, the surface roughness of the membrane was enhanced and the anti-swelling property of the polyelectrolyte multilayer was also improved. The hydrophilic [(PDDA/PAA-CSH)(2.5)]Cl-+(-) membrane was then converted to the hydrophobic membrane through the counterion exchange between Cl- and perfluomoctanate (PFO-) ions. The obtained [(PDDA/PAA-CSH)(2.5)]+PFO- membrane has a water contact angle of 118 degrees, which can be used to separate dyes from ethanol. Both the separation performance and stability of the polyelectrolyte multilayer membrane were improved through the in situ growth of calcium silicate hydrate nanoparticles and counterion exchange by perfluomoctanate ions. Therefore, this strategy may open a new avenue to prepare organic solvent nanofiltration membranes.

Keyword:

Organic solvent nanofiltration Counterion exchange Hydrophobic Polyelectrolyte multilayer membrane Enhanced performance

Author Community:

  • [ 1 ] [Lu, Yahua]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Qin, Zhenping]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Naixin]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [An, Quan-Fu]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Guo, Hongxia]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 王乃鑫

    [Wang, Naixin]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Guo, Hongxia]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

Show more details

Related Keywords:

Source :

JOURNAL OF MEMBRANE SCIENCE

ISSN: 0376-7388

Year: 2021

Volume: 620

9 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:96

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:611/5305846
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.