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作者:

Theerthagiri, Jayaraman (Theerthagiri, Jayaraman.) | Murthy, Arun Prasad (Murthy, Arun Prasad.) | Lee, Seung Jun (Lee, Seung Jun.) | Karuppasamy, K. (Karuppasamy, K..) | Arumugam, Senthil Raja (Arumugam, Senthil Raja.) | Yu, Yiseul (Yu, Yiseul.) | Hanafiah, Marlia M. (Hanafiah, Marlia M..) | Kim, Hyun-Seok (Kim, Hyun-Seok.) | Mittal, Vikas (Mittal, Vikas.) | Choi, Myong Yong (Choi, Myong Yong.)

收录:

EI SCIE

摘要:

Continuous advancements in the field of energy conversion and storage, including the development, evaluation of abundant and inexpensive materials with good electrochemical performance, aim to meet the future energy demands. Transition metal phosphides (TMPs) have recently emerged as excellent energy conversion and storage materials due to their highly active surface sites, electrical conductivity, thermal and structural stability. TMPs exhibit numerous other desirable properties, like hardness and chemical stability, which result from the presence of strong M - P bonds in the molecules. In this work, comprehensive review of recent advancements in research concerning TMPs and their applications in the area of energy conversion and storage was conducted. Additionally, the frequently employed synthetic strategies for the production of TMPs were investigated. Particularly, hydrogen and oxygen evolution reactions (HER and OER), dye-sensitized solar cells for energy conversion and storage, lithium-ion batteries, and supercapacitors were examined. TMPs display remarkable electrochemical behavior due to the synergistic effects of various compositions and surface structures. Moreover, the M-centers and P-sites possess high electrocatalytic activity. The P-sites of phosphides are negatively charged; thus, they attract protons, enhancing the HER/OER activities. Eventhough platinum-based electrocatalysts perform best in HER, their bifunctional properties have not been extensively studied due to poor OER activities. In energy storage, TMPs used as efficient and stable electrodes owing to their low charge-discharge potentials, high theoretical specific capacities, and a decreased ion-diffusion pathway. Finally, the challenges, future perspectives in the area of energy are discussed and several approaches for the improvement of multifunctional TMPs are proposed.

关键词:

Dye-sensitized solar cells Hydrogen evolution reaction Lithium ion battery Oxygen evolution reaction Supercapacitors Transition metal phosphides

作者机构:

  • [ 1 ] [Theerthagiri, Jayaraman]Gyeongsang Natl Univ, Dept Chem, Jinju 52828, South Korea
  • [ 2 ] [Lee, Seung Jun]Gyeongsang Natl Univ, Dept Chem, Jinju 52828, South Korea
  • [ 3 ] [Yu, Yiseul]Gyeongsang Natl Univ, Dept Chem, Jinju 52828, South Korea
  • [ 4 ] [Choi, Myong Yong]Gyeongsang Natl Univ, Dept Chem, Jinju 52828, South Korea
  • [ 5 ] [Theerthagiri, Jayaraman]Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 52828, South Korea
  • [ 6 ] [Lee, Seung Jun]Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 52828, South Korea
  • [ 7 ] [Yu, Yiseul]Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 52828, South Korea
  • [ 8 ] [Choi, Myong Yong]Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 52828, South Korea
  • [ 9 ] [Murthy, Arun Prasad]Vellore Inst Technol, Sch Adv Sci, Dept Chem, Vellore 632014, Tamil Nadu, India
  • [ 10 ] [Karuppasamy, K.]Dongguk Univ, Div Elect & Elect Engn, Seoul 04620, South Korea
  • [ 11 ] [Kim, Hyun-Seok]Dongguk Univ, Div Elect & Elect Engn, Seoul 04620, South Korea
  • [ 12 ] [Arumugam, Senthil Raja]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 13 ] [Hanafiah, Marlia M.]Univ Kebangsaan Malaysia, Fac Sci & Technol, Dept Earth Sci & Environm, Bangi 43600, Selangor, Malaysia
  • [ 14 ] [Hanafiah, Marlia M.]Univ Kebangsaan Malaysia, Inst Climate Change, Ctr Trop Climate Change Syst, Bangi 43600, Selangor, Malaysia
  • [ 15 ] [Mittal, Vikas]Khalifa Univ, Dept Chem Engn, Abu Dhabi, U Arab Emirates

通讯作者信息:

  • [Choi, Myong Yong]Gyeongsang Natl Univ, Dept Chem, Jinju 52828, South Korea;;[Choi, Myong Yong]Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 52828, South Korea;;[Mittal, Vikas]Khalifa Univ, Dept Chem Engn, Abu Dhabi, U Arab Emirates

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来源 :

CERAMICS INTERNATIONAL

ISSN: 0272-8842

年份: 2021

期: 4

卷: 47

5 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:8

被引次数:

WoS核心集被引频次: 137

SCOPUS被引频次: 139

ESI高被引论文在榜: 2 展开所有

  • 2022-3
  • 2022-1

万方被引频次:

中文被引频次:

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