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Author:

Jia, Miao (Jia, Miao.) | Jin, Yuhong (Jin, Yuhong.) | Zhao, Chenchen (Zhao, Chenchen.) | Chang, Qianqian (Chang, Qianqian.) | Zhao, Peizhu (Zhao, Peizhu.) | Wang, Hao (Wang, Hao.) | Jia, Mengqiu (Jia, Mengqiu.)

Indexed by:

EI Scopus SCIE

Abstract:

Traditional metal selenide was used as sodium ion battery anode on account of its high specific capacity and large layer spacing. Here, ZnSe/rGO composites are synthesized through a facile one-step hydrothermal method using relatively environmentally friendly raw materials. The obtained ZnSe nanoparticles with a diameter of about 50 nm, which evenly distributed on the three-dimensional graphene sheet. Electrochemical test results show improved performance, under a current density of 100 mA g(-1), the capacity can still remain 276.6 mA h g(-1) after 100 cycles. For rate performance, when the current density are under 0.1, 0.2, 0.5, 1, 2, 5 and 10 A g(-1), the capacity can remain 411.6, 385.9, 340.1, 293.9, 239.4,179.2 and 119.4 mA h g(-1), respectively. Furthermore, under a large current density of 500 mA g(-1), it can remain a reversible capacity of 119.4 mA h g(-1). In addition, the calculation of pseudocapacitance shows that it is helpful to achieve pleasing rate capability and long cyclic stability. As a result of its high specific surface area and enhanced electronic conductivity, an improved performance can be obtain, furthermore can well alleviate the volume expansion of the composite. (C) 2020 Elsevier B.V. All rights reserved.

Keyword:

Reduced graphene Sodium ion battery Pseudocapacitance ZnSe

Author Community:

  • [ 1 ] [Jia, Miao]Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 2 ] [Chang, Qianqian]Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 3 ] [Zhao, Peizhu]Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 4 ] [Jia, Mengqiu]Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China
  • [ 5 ] [Jin, Yuhong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Zhao, Chenchen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Hao]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Jin, Yuhong]Beijing Univ Technol, Beijing Guyue New Mat Res Inst, Beijing 100124, Peoples R China
  • [ 9 ] [Zhao, Chenchen]Beijing Univ Technol, Beijing Guyue New Mat Res Inst, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Jia, Mengqiu]Beijing Univ Chem Technol, Beijing Key Lab Electrochem Proc & Technol Mat, Beijing 100029, Peoples R China;;[Jin, Yuhong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2021

Volume: 854

6 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:116

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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