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作者:

Zong, Xupeng (Zong, Xupeng.) | Niu, Lijuan (Niu, Lijuan.) | Jiang, Wenshuai (Jiang, Wenshuai.) | Yu, Yanmin (Yu, Yanmin.) | An, Li (An, Li.) | Qu, Dan (Qu, Dan.) | Wang, Xiayan (Wang, Xiayan.) | Sun, Zaicheng (Sun, Zaicheng.) (学者:孙再成)

收录:

EI SCIE

摘要:

Building a donor-acceptor (D–A) type polymeric carbon nitride is a promising way for synthesizing high-performance photocatalysts. Compared with introducing an acceptor unit, incorporating donor blocks can effectively extend the absorption range without altering H2 production sites. Herein, we report a facile method to construct a D-A structure by introducing the creatinine-derived moiety (CDM) into melem networks via copolymerization of creatinine and urea. CDM units arouse a new absorption band at 500 nm and result in the LUMO and HOMO distribute at melem and CDM unit, which promotes the charge spatial separation. The optimal photocatalytic activity of 9454 μmolg−1 h−1 can be achieved. That does not only improve the apparent quantum yield (AQE) at 420 nm from 3.80 % to 8.41 % but also raises the AQE at 500 nm from 0.71 % to 4.57 %. This strategy provides the potential to extend the further visible light response with a decent performance. © 2021 Elsevier B.V.

关键词:

Carbon nitride Hydrogen production Photocatalytic activity Urea

作者机构:

  • [ 1 ] [Zong, Xupeng]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 2 ] [Niu, Lijuan]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 3 ] [Jiang, Wenshuai]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 4 ] [Yu, Yanmin]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 5 ] [An, Li]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 6 ] [Qu, Dan]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 7 ] [Wang, Xiayan]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China
  • [ 8 ] [Sun, Zaicheng]Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Biology, Beijing University of Technology, 100 Pingleyuan, Chaoyang District, Beijing; 100124, China

通讯作者信息:

  • [qu, dan]center of excellence for environmental safety and biological effects, beijing key laboratory for green catalysis and separation, department of chemistry and biology, beijing university of technology, 100 pingleyuan, chaoyang district, beijing; 100124, china

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来源 :

Applied Catalysis B: Environmental

ISSN: 0926-3373

年份: 2021

卷: 291

2 2 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:7

被引次数:

WoS核心集被引频次: 0

SCOPUS被引频次: 49

ESI高被引论文在榜: 0 展开所有

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