The　fluorescent　temperature-sensitive　mesoporous　materials　with　core-shell　structured　feature　were　synthesized　through　self-assembly　method,　in　which,　bimodal　mesoporous　SiO2　materials　(BMMs)　were　used　as　a　core　and　poly(N-isopropyl　acryl-acrylamide)-co-poly(acrylic　acid)　as　a　shell.　Especially,　the　2-[3-(triethoxysilyl)　propyl-1H-Benz][de]isoquinoline-1,3(2H)-dione　(PID)　as　fluorescent　molecule　was　cooperated　into　the　BMMs　by　one-pot　(doped)　or　two-step　(grafted)　methods.　Using　ibuprofen　as　a　model　drug,　and　the　PID-doped　P@BMMs　and　PID-grafted　P@BMMs　as　the　carriers,　the　drug　releasing　performances　show　the　strong　fluorescent　properties　and　temperature-responsive　behaviors.　These　results　suggest　that　the　prepared　fluorescent　nanocomposites　should　be　a　promise　drug　carrier　for　a　potential　drug　delivery.