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作者:

Zhang, Xuehua (Zhang, Xuehua.) | Lin, Lin (Lin, Lin.) | Qu, Dan (Qu, Dan.) | Yang, Jiangong (Yang, Jiangong.) | Weng, Yuxiang (Weng, Yuxiang.) | Wang, Zhuan (Wang, Zhuan.) | Sun, Zaicheng (Sun, Zaicheng.) (学者:孙再成) | Chen, Yong (Chen, Yong.) | He, Tao (He, Tao.)

收录:

EI SCIE

摘要:

Developing highly efficient photocatalysts for solar-fuels production under visible-light irradiation is of great promise, but still remains a big challenge. In this work, we use g-C3N4 incorporated with carbon dots as the photosensitizer to couple with tetra(4-carboxyphenyl)porphyrin iron(III) chloride (FeTCPP) molecular catalyst. The obtained g-C3N4-C-0.05/FeTCPP hybrid photocatalyst exhibits high activity for the solar-fuels production of CO and H-2 under visible-light irradiation, with CO yield of 23.1 mmol/g and Hy yield of 71.1 mmol/g in 6 h. The enhanced mechanism has been studied by various techniques like photocurrent response, photoluminescence and mid-infrared femtosecond transient absorption. The presence of trace amount of carbon dots in the system can provide an alternative channel for the electron transfer, i.e., from g-C3N4 to FeTCPP via the CDs. Accordingly, the interfacial charge separation and electron transfer can be promoted, leading to enhanced photocatalytic performance of the g-C3N4-C-x/FeTCPP hybrid photocatalysts.

关键词:

Carbon dots Charge separation g-C3N4 Interfacial electron transfer Tetra(4-carboxyphenyl)porphyrin iron(III) chloride

作者机构:

  • [ 1 ] [Zhang, Xuehua]Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
  • [ 2 ] [Lin, Lin]Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
  • [ 3 ] [He, Tao]Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China
  • [ 4 ] [Qu, Dan]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Sun, Zaicheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 6 ] [Chen, Yong]Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
  • [ 7 ] [Weng, Yuxiang]Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
  • [ 8 ] [Wang, Zhuan]Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
  • [ 9 ] [Weng, Yuxiang]Chinese Acad Sci, CAS Key Lab Soft Matter Phys, Inst Phys, Beijing 100190, Peoples R China
  • [ 10 ] [Wang, Zhuan]Chinese Acad Sci, CAS Key Lab Soft Matter Phys, Inst Phys, Beijing 100190, Peoples R China
  • [ 11 ] [Weng, Yuxiang]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 12 ] [He, Tao]Univ Chinese Acad Sci, Beijing 100049, Peoples R China

通讯作者信息:

  • 孙再成

    [He, Tao]Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China;;[Sun, Zaicheng]Beijing Univ Technol, Dept Chem & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Chen, Yong]Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China;;[Wang, Zhuan]Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China;;[Wang, Zhuan]Chinese Acad Sci, CAS Key Lab Soft Matter Phys, Inst Phys, Beijing 100190, Peoples R China;;[He, Tao]Univ Chinese Acad Sci, Beijing 100049, Peoples R China

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来源 :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

年份: 2020

卷: 265

2 2 . 1 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:33

JCR分区:1

被引次数:

WoS核心集被引频次: 36

SCOPUS被引频次: 39

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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