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作者:

Jia, Miao (Jia, Miao.) | Jin, Yuhong (Jin, Yuhong.) | Zhao, Chenchen (Zhao, Chenchen.) | Chang, Qianqian (Chang, Qianqian.) | Zhao, Peizhu (Zhao, Peizhu.) | Wang, Hao (Wang, Hao.) | Jia, Mengqiu (Jia, Mengqiu.)

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EI Scopus SCIE

摘要:

Traditional metal selenide was used as sodium ion battery anode on account of its high specific capacity and large layer spacing. Here, ZnSe/rGO composites are synthesized through a facile one-step hydrothermal method using relatively environmentally friendly raw materials. The obtained ZnSe nanoparticles with a diameter of about 50 nm, which evenly distributed on the three-dimensional graphene sheet. Electrochemical test results show improved performance, under a current density of 100 mA g−1, the capacity can still remain 276.6 mA h g−1 after 100 cycles. For rate performance, when the current density are under 0.1, 0.2, 0.5, 1, 2, 5 and 10 A g−1, the capacity can remain 411.6, 385.9, 340.1, 293.9, 239.4, 179.2 and 119.4 mA h g−1, respectively. Furthermore, under a large current density of 500 mA g−1, it can remain a reversible capacity of 119.4 mA h g−1. In addition, the calculation of pseudocapacitance shows that it is helpful to achieve pleasing rate capability and long cyclic stability. As a result of its high specific surface area and enhanced electronic conductivity, an improved performance can be obtain, furthermore can well alleviate the volume expansion of the composite. © 2020 Elsevier B.V.

关键词:

Graphene II-VI semiconductors Metal ions Selenium compounds Anodes Current density Zinc Selenide Sodium-ion batteries

作者机构:

  • [ 1 ] [Jia, Miao]Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing; 100029, China
  • [ 2 ] [Jin, Yuhong]The College of Materials Science and Engineering, Beijing University of Technology, Beijing; 100124, China
  • [ 3 ] [Jin, Yuhong]Beijing Guyue New Materials Research Institute, Beijing University of Technology, Beijing; 100124, China
  • [ 4 ] [Zhao, Chenchen]The College of Materials Science and Engineering, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Zhao, Chenchen]Beijing Guyue New Materials Research Institute, Beijing University of Technology, Beijing; 100124, China
  • [ 6 ] [Chang, Qianqian]Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing; 100029, China
  • [ 7 ] [Zhao, Peizhu]Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing; 100029, China
  • [ 8 ] [Wang, Hao]The College of Materials Science and Engineering, Beijing University of Technology, Beijing; 100124, China
  • [ 9 ] [Jia, Mengqiu]Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing; 100029, China

通讯作者信息:

  • [jin, yuhong]the college of materials science and engineering, beijing university of technology, beijing; 100124, china;;[jin, yuhong]beijing guyue new materials research institute, beijing university of technology, beijing; 100124, china

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来源 :

Journal of Alloys and Compounds

ISSN: 0925-8388

年份: 2021

卷: 854

6 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:116

JCR分区:1

被引次数:

WoS核心集被引频次: 0

SCOPUS被引频次: 17

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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