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Diatomite is an inorganic nonmetallic mineral material. Due to unique ordered pore structures, applications of diatomite have been realized in chemical engineering and building materials industries. The application of diatomite was usually limited by its specific surface area (about 18-28 m2/g). Through the functionalization, diatomite materials could be vested with a certain property, thus improving the performance in environment treatment and advancing applications in the field of energy and bioengineering. Therefore, functionalization of diatomite has become a research focus. In recent years, researches on functionalization of diatomite mainly focus on three areas: noncovalent functionalization, covalent functionalization and chemical conversion of diatomite. Normally, noncovalent functionalization indicate that using nano metal oxides and metal oxygenates to modify diatomite and the functionalized diatomite can be used in the field of energy, water treatment and sensors. Covalent functionalization of diatomite refers to modifying diatomite with functional monomer through the connection of Si-O covalent bond based on Si-O tetrahedron and Si-OH of diatomite. Functional monomers are classified into silicates and silane coupling agents. Silane coupling agents connect to diatomite through Si-OH, and it could also be used to connect other functional groups to obtain excellent properties. Covalent functionalized diatomite is commonly used in the fields of energy, sensor and water treatment. The chemical conversion of diatomite to silicon source is the other functionalization met-hod. Silicon keeps the morphology of diatomite and can be used in the field of energy and bioengineering. Functionalization of diatomite is the key to realize the application of diatomite materials in emerging fields. Therefore, researches on diatomite functionalization would advance the application of diatomite and promote the development of emerging areas. Here, the progress of diatomite functionalization at home and abroad in recent years are summarized. The functionalization routes and their applications are introduced in detail in order to provide reference for advanced diatomite functionalization routes and their applications. © 2020, Materials Review Magazine. All right reserved.
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