In　this　work,　Fe2O3　supported　single　atom　Pt　(x　Pt1/Fe2O3,　x　=　0.25　and　0.5　wt%)　catalysts　(SACs)　are　synthesized　via　a　novel　and　simple　impregnation-pyrolysis　method.　HAADF-STEM　images　show　that　Pt　is　atomically　dispersed　on　the　surface　of　Fe2O3.　All　samples　exhibit　good　light-thermal　conversion　efficiency,　which　can　increase　the　surface　temperature　of　catalysts　to　210　degrees　C.　The　0.5　Pt1/Fe2O3　exhibits　the　best　photothermal　catalytic　performance　(the　toluene　conversion　and　CO2　yield　are　95　%　and　87　%,　respectively)　for　toluene　oxidation　under　the　irradiation　of　simulated　sunlight　with　light　intensity　of　720　mW/cm2,　which　is　attributed　to　its　good　lightthermal　conversion　efficiency　and　low　temperature　reducibility.　The　Vis-IR　light　plays　a　critical　role　in　the　photothermal　catalytic　oxidation　of　toluene　in　the　whole　solar　spectrum.　Furthermore,　the　possible　photothermal　catalytic　reaction　pathway　of　toluene　oxidation　is　proposed　based　on　the　TD-GC/MS　and　in-situ　DRIFTS　experiments.