The　heterogeneous　Fenton-like　process　with　bimetallic　chelated　magnetic　chitosan　aerogel　(Cu-Fe@CTS)　as　catalyst　was　applied　to　treat　pre-coagulated　leachate　nanofiltration　concentrate.　The　process　conditions　were　optimized　by　Box-Behnken　Design　(BBD)　and　the　maximum　UV254　removal　reached　96.06%　under　the　conditions　of　temperature　87.62　degrees　C,　oxidant　dosage　0.2395　mol/L　and　catalyst　dosage　1　g/L.　The　TOC　concentration　was　reduced　from　847.5　to　99.7　mg/L　and　COD　concentration　was　reduced　from　1625　to　464　mg/L.　The　threedimensional　(3D)　fluorescence　analysis　showed　that　most　of　Fulvic　acid-like　(FA-like)　was　removed.　The　adsorption　experiment　showed　that　the　catalyst　reached　the　adsorption　balanced　after　60　min　and　the　corresponding　FA　adsorption　removal　reached　14.1%.　The　addition　of　Tert-butanol　(TBA)　reduced　the　FA　removal　by　59.4%,　indicating　that　the　hydroxyl　radicals　(center　dot　OH)　was　the　main　active　species.　Experiments　of　the　center　dot　OH　capture　at　different　pH　showed　that　the　Fenton-like　system　produced　more　center　dot　OH　at　pH　of　4,　at　which　the　maximum　FA　removal　was　96.61%,　while　the　FA　removal　still　reached　94.26%　at　pH　of　7.　The　center　dot　OH　capture　at　different　temperature　showed　that　the　Fenton-like　system　produced　more　center　dot　OH　at　90　degrees　C.　KI　and　TBA　shielding　experiments　showed　that　center　dot　OH　was　produced　on　the　catalyst　surface　rather　than　being　produced　by　catalysis　of　free　metal　ions　in　the　solution.