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作者:

Zong, Peng-an (Zong, Peng-an.) | Mao, Zhengdong (Mao, Zhengdong.) | Ou, Yixiang (Ou, Yixiang.) | Shi, Taifeng (Shi, Taifeng.) | Wang, Zhiweng (Wang, Zhiweng.) | Zhang, Qihao (Zhang, Qihao.) | Zhang, Peng (Zhang, Peng.) | Wan, Chunlei (Wan, Chunlei.)

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EI Scopus SCIE

摘要:

Filling the icosahedral lattice holes of the cage-compound CoSb3 with alkali, alkaline-earth and rare-earth metal atoms can endow CoSb3 with the transport characteristic of "phonon-glass-electron-crystal". However, the filler atoms greatly increase the cost in raw material as well as fabrication complexity. In this work, we embedded FeCl3-intercalated graphene nanolayers into polycrystalline CoSb3 by a solution-dispersion method combined with spark plasma sintering technology. The graphene nanosheets were mainly distributed in grain boundaries. Due to the increased carrier concentration and mobility, the electrical conductivity was improved. Meanwhile, due to the enhanced interfacial phonon scattering, the lattice thermal conductivity was effectively suppressed. The thermoelectric figure of merit of the nanocomposite reached 0.6 at a mass content of 0.2 % FeCl3-intercalated graphene nanolayers, outperforming all reported values of binary CoSb3 based nanocomposites, and even comparable to that of commercially used filled p-type Fe3CoSb12. This work provides a promising strategy for low-cost fabrication of p-type skutterudites.

关键词:

Thermoelectric Nanocomposite Intercalate Graphene Skutterudite

作者机构:

  • [ 1 ] [Zong, Peng-an]Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China
  • [ 2 ] [Mao, Zhengdong]Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China
  • [ 3 ] [Shi, Taifeng]Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China
  • [ 4 ] [Wang, Zhiweng]Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China
  • [ 5 ] [Zong, Peng-an]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
  • [ 6 ] [Wan, Chunlei]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
  • [ 7 ] [Ou, Yixiang]Beijing Acad Sci & Technol, Beijing Radiat Ctr, Beijing 100875, Peoples R China
  • [ 8 ] [Zhang, Qihao]Shanghai Inst Ceram, Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
  • [ 9 ] [Zhang, Qihao]Leibniz Inst Solid State & Mat Res, Inst Metall Mat, D-01069 Dresden, Germany
  • [ 10 ] [Zhang, Peng]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zong, Peng-an]Nanjing Tech Univ, Coll Mat Sci & Engn, Nanjing 210009, Jiangsu, Peoples R China;;[Wan, Chunlei]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China

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来源 :

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

ISSN: 0955-2219

年份: 2021

期: 13

卷: 41

页码: 6523-6530

5 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:116

JCR分区:1

被引次数:

WoS核心集被引频次: 9

SCOPUS被引频次: 10

ESI高被引论文在榜: 0 展开所有

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