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作者:

Liang, Wenjun (Liang, Wenjun.) (学者:梁文俊) | Zhu, Yuxue (Zhu, Yuxue.) | Ren, Sida (Ren, Sida.) | Li, Qinglei (Li, Qinglei.) | Song, Liyun (Song, Liyun.) | Shi, Xiujuan (Shi, Xiujuan.)

收录:

SCIE

摘要:

Ru/TiO2 and Ru-Ce/TiO2 catalysts were prepared by the equal-volume impregnation method to test their catalytic oxidation of chlorobenzene(CB), with the aim to investigate the effect of Ce addition on the redox capacity of the catalysts under the premise of reducing the content of noble metals. It was found that the introduction of Ce conserved the high catalytic efficiency of the catalyst while reducing the content of noble metal, and the catalysis of CB was greatly improved at low temperatures. Compared with the 0.4Ru/TiO2 catalyst, the T-10 and T-90 of the 0.4Ru-1.0Ce/TiO2 catalyst decreased by 50 degrees C and 60 degrees C respectively. It presented high reaction rate at 170. with an increase from 1.21 x 10(-8) mol/min.m(2) for the 0.4Ru/TiO2 catalyst to 10.45 x 10(-8) mol/min.m(2), making it even better than the 2.0Ru/TiO2 catalyst. The structure and morphology of the Ru/TiO2 catalyst did not change with the Ce doping and the mesoporous structure of the catalysts was maintained. CeO2 can not only store and release oxygen, but also improve the activity and dispersion of precious metal loaded. The formation of Ru-O-Ce under the interaction between CeO2 and Ru species promoted electron transfer and improved the mobility of surface oxygen, thus forming RuOx with higher valance. The introduction of Ce improved the yield of COx and selectivity towards inorganic chlorine (HCl and Cl-2) and prevented the catalyst from producing more chlorinated by-products, thus greatly reducing the chance of producing more toxic dioxins.

关键词:

Catalytic oxidation Cerium Chlorobenzene Ru-Ce/TiO2 Ruthenium

作者机构:

  • [ 1 ] [Liang, Wenjun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Zhu, Yuxue]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Ren, Sida]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Qinglei]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Song, Liyun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Shi, Xiujuan]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

通讯作者信息:

  • 梁文俊

    [Liang, Wenjun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

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来源 :

APPLIED CATALYSIS A-GENERAL

ISSN: 0926-860X

年份: 2021

卷: 623

5 . 5 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:7

被引次数:

WoS核心集被引频次: 21

SCOPUS被引频次: 25

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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