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作者:

Zhao, Chen (Zhao, Chen.) | Zhou, Awu (Zhou, Awu.) | Dou, Yibo (Dou, Yibo.) | Zhou, Jian (Zhou, Jian.) | Bai, Jinquan (Bai, Jinquan.) | Li, Jian-Rong (Li, Jian-Rong.) (学者:李坚)

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EI Scopus SCIE

摘要:

Developing efficient photocatalysts for CO2 reduction into value-added chemical feedstocks is of significance. Heterojunction photocatalysts are promising candidates but still suffering from the insufficient electron-hole pair separation issues. Herein, a strategy that dual metal?organic frameworks (MOFs) template-directed fabrication of carbon-supported heterojunction, C-In2O3@MO (MO = ZnO, Co3O4, and ZnCo2O4) with tunable band matching structure was developed. The resultant hollow-structured C-In2O3@ZnCo2O4 shows high CO2 reduction activity towards CO (44.1 ?mol g1 h-1) with a selectivity of 66%. The superior performance of this material could be ascribed to the suitable energy band matching and efficient internal charge transfer on p-n heterojunction, which facilitates electron-hole separation. Meanwhile, the hollow cavity not only improved light-harvesting capability through multiple light reflection and scattering in the internal voids but also provided large surface area for exposing active sites to promoting the activation of CO2. This study thus proposes a feasible approach to adjust the heterojunction structure of photocatalysts to achieve efficient CO2 reduction reaction. Superscript/Subscript Available</comment

关键词:

template Photocatalytic CO < sub > 2 < Heterojunction Interface integration Dual metal?organic frameworks (MOFs) Hollow-structure sub > reduction

作者机构:

  • [ 1 ] [Dou, Yibo]Beijing Univ Technol, Fac Environm & Life, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Dou, Yibo]Beijing Univ Technol, Fac Environm & Life, Dept Chem & Chem Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Jian-Rong]Beijing Univ Technol, Fac Environm & Life, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Jian-Rong]Beijing Univ Technol, Fac Environm & Life, Dept Chem & Chem Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 李坚

    [Dou, Yibo]Beijing Univ Technol, Fac Environm & Life, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Li, Jian-Rong]Beijing Univ Technol, Fac Environm & Life, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

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来源 :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

年份: 2021

卷: 416

1 5 . 1 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:87

JCR分区:1

被引次数:

WoS核心集被引频次: 69

SCOPUS被引频次:

ESI高被引论文在榜: 0 展开所有

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