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作者:

Zhao, Jingteng (Zhao, Jingteng.) | Zhang, Xu (Zhang, Xu.) | Liang, Yuan (Liang, Yuan.) | Han, Zhijie (Han, Zhijie.) | Liu, Shiqi (Liu, Shiqi.) | Chu, Weiqin (Chu, Weiqin.) | Yu, Haijun (Yu, Haijun.) (学者:尉海军)

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EI Scopus SCIE

摘要:

Lithium-rich layered oxides (LLOs) are fascinating high-energy-density cathode materials for next-generation lithium-ion batteries (LIBs). However, the high voltage causes severe decomposition of conventional carbonate-based electrolytes at LLOs' surfaces, often producing a non-uniform, unstable, and non-protective cathode-electrolyte interphase (CEI), hindering the Li+ diffusion and reducing the electrochemical efficiency. Various side reactions, such as the release of lattice oxygen, dissolution of transition metals (especially manganese), and irreversible structural transformations, also occur and severely attenuate the electrochemical performance. Electrolyte additives provide a facile and effective approach to optimize the battery performance by in situ regulating the physical/chemical structures/properties of CEI. This paper reviews the research progress in functional electrolyte additives for LLOs and discusses the mechanisms of CEI construction with diverse functions. Finally, we tentatively propose suggestions to construct CEI by screening and customizing electrolyte additives to promote the large-scale application of LLOs for LIBs.

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作者机构:

  • [ 1 ] [Zhao, Jingteng]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Xu]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Liang, Yuan]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Han, Zhijie]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Shiqi]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Chu, Weiqin]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Yu, Haijun]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Zhao, Jingteng]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 9 ] [Zhang, Xu]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 10 ] [Liang, Yuan]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 11 ] [Han, Zhijie]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 12 ] [Liu, Shiqi]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 13 ] [Chu, Weiqin]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 14 ] [Yu, Haijun]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

通讯作者信息:

  • 尉海军

    [Yu, Haijun]Beijing Univ Technol, Fac Mat & Mfg, Inst Adv Battery Mat & Devices, Minist Educ, Beijing 100124, Peoples R China;;[Yu, Haijun]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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来源 :

ACS ENERGY LETTERS

ISSN: 2380-8195

年份: 2021

期: 7

卷: 6

页码: 2552-2564

2 2 . 0 0 0

JCR@2022

JCR分区:1

被引次数:

WoS核心集被引频次: 99

SCOPUS被引频次: 100

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