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作者:

Fan, Yan (Fan, Yan.) | Liu, Yanru (Liu, Yanru.) | Hu, Xiang (Hu, Xiang.) | Sun, Zhirong (Sun, Zhirong.)

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摘要:

The metal organic framework derived materials (CoFe2O4@NC) activated peroxymonosulfate (PMS) to degrade Norfloxacin (NOR) owing to the characteristics of high surface area (109.658 m(2) g(-1)) and abundant mesoporous structure. The characterization results demonstrated that the optimal ratio of bimetal and of bimetallic to organic ligands (M/O) had good crystal structure and stability (Fe/Co = 3:1, M/O = 2:1). Moreover, NOR (10 mg L-1) removal of 98.78% was achievable in 60 min with an optimum concentration of PMS (0.32 mM) and dosage of CoFe2O4@NC (0.1 g L-1). The radical quenching results suggested that SO4 center dot(-), center dot OH and O-1(2) functioned in the presence of the system certificated by XPS spectra. The presence of Cl- and CO32-/HCO3- promoted the catalyst reaction. The recoverability revealed high removal efficiency of NOR of 93.55% could still be maintained. Furthermore, four pathways of NOR degradation were proposed, including dehydroxylation, defluorination, quinolone group conversion and piperazine ring transformation, which were attributed to the synergy of reactive oxygen species. The above results highlight that the method is of great significance to the practical application of heterogeneous catalysts in aqueous solutions. (C) 2021 Elsevier Ltd. All rights reserved.

关键词:

Metal organic framework Norfloxacin Peroxomonosulfate Radical Oxidative degradation Water treatment

作者机构:

  • [ 1 ] [Fan, Yan]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
  • [ 2 ] [Liu, Yanru]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
  • [ 3 ] [Hu, Xiang]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
  • [ 4 ] [Sun, Zhirong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Hu, Xiang]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China

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来源 :

CHEMOSPHERE

ISSN: 0045-6535

年份: 2021

卷: 275

8 . 8 0 0

JCR@2022

ESI学科: ENVIRONMENT/ECOLOGY;

ESI高被引阀值:94

JCR分区:1

被引次数:

WoS核心集被引频次: 1

SCOPUS被引频次: 38

ESI高被引论文在榜: 0 展开所有

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