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作者:

Niu, Lijuan (Niu, Lijuan.) | Liu, Guohua (Liu, Guohua.) | Li, Yifan (Li, Yifan.) | An, Jiawen (An, Jiawen.) | Zhao, Boyuan (Zhao, Boyuan.) | Yang, Jingsu (Yang, Jingsu.) | Qu, Dan (Qu, Dan.) | Wang, Xiayan (Wang, Xiayan.) | An, Li (An, Li.) | Sun, Zaicheng (Sun, Zaicheng.) (学者:孙再成)

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EI Scopus SCIE

摘要:

Transition metal alloys and their compounds have been drafted as relatively economic and high-activity non-noble metal electrocatalysts for the oxygen reduction reaction (ORR). However, the stability of catalysts is regarded as a critical issue for practical application. Here, we report CoNi alloy nanoparticles embedded in a nitrogen-doped graphite carbon nanotube (CoNi@N-GCNT-FD) electrocatalyst, which is synthesized from metal precursors and dicyandiamide nanofibers formed by freeze-drying pretreatment. The electrocatalyst exhibits remarkable ORR performance (a positive onset potential at 0.90 V vs reversible hydrogen electrode (RHE), a half-wave potential at 0.84 V vs RHE, and a high limiting current density (6.4 mA cm(-2))) in an alkaline medium. The outstanding ORR catalytic behavior is attributable to the properties with a high specific surface area and the collaborative influence between a CoNi alloy and a nanotube protective layer. The CoNi@N-GCNT-FD also displays antimethanol toxicity and good stability over 10,000 cycles, attributed to the unique structure of N-GCNT that is more conducive to mass transfer and protects the alloy particles from corrosion under harsh conditions. This simple route can be widely used to prepare other alloy electrocatalysts with relatively economic value and high performance in power conversion and stockpile device fields.

关键词:

CoNi alloy N-doped graphite carbon nanotubes nonprecious metal catalysts oxygen reduction reaction electrocatalyst

作者机构:

  • [ 1 ] [Niu, Lijuan]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, Guohua]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Yifan]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [An, Jiawen]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 5 ] [Zhao, Boyuan]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 6 ] [Yang, Jingsu]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 7 ] [Qu, Dan]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 8 ] [Wang, Xiayan]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 9 ] [An, Li]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 10 ] [Sun, Zaicheng]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

通讯作者信息:

  • 孙再成

    [An, Li]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[Sun, Zaicheng]Beijing Univ Technol, Fac Environm & Life, Ctr Excellence Environm Safety & Biol Effects, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

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来源 :

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

ISSN: 2168-0485

年份: 2021

期: 24

卷: 9

页码: 8207-8213

8 . 4 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:96

JCR分区:1

被引次数:

WoS核心集被引频次: 25

SCOPUS被引频次: 26

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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