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作者:

Liang, Jumei (Liang, Jumei.) | Zhang, Lijuan (Zhang, Lijuan.) | XiLi, Dege (XiLi, Dege.) | Kang, Jing (Kang, Jing.)

收录:

EI SCIE

摘要:

As an anode material for sodium ion batteries (SIBs), SnO2 has a large theoretical capacity of 1378 mA h g(-1). However, the poor cyclic stability caused by its serious volume expansion during the charge/discharge process has become the biggest obstacle to its practicability. In this paper, one-dimensional tubular SnO2@TiO2 core-shell nanocomposites were designed and synthesized for the first time to inhibit the volume change of SnO2 during (de)sodiation process, thus greatly improving its cyclic stability. The SnO2@TiO2 anode provides a capacity of 316 mA h g(-1) after 50 cycles at a current density of 50 mA g(-1) and the initial Coulombic efficiency (ICE) is 49.7%. By contrast, the corresponding figures are only 200 mA h g(-1) and 29% for pristine SnO2, 179 mA h g(-1) and 32% for TiO2 nanotube, respectively. XPS, TEM and HR-TEM techniques were used to analyze the electronic and geometric structures of the composites. The excellent electrochemical performance of SnO2@TiO2 nanocomposites were further demonstrated by kinetic analysis and the pseudo-capacitive properties of SnO2@TiO2 electrodes were calculated from the aspect of kinetics. It could be inferred that the reasonable structure design is conducive to improve the sodium storage performance of the SnO2@TiO2 composites, and may provide a good solution for further development of SIBs. (C) 2020 Elsevier Ltd. All rights reserved.

关键词:

Electrochemical performance SnO2@TiO2 Sodium ion batteries

作者机构:

  • [ 1 ] [Liang, Jumei]Beijing Univ Technol, Ctr Excellence Environm Safety & Biol Effects, Sch Environm & Energy Engn, Dept Chem & Chem Engn,Beijing Key Lab Green Catal, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Lijuan]Beijing Univ Technol, Ctr Excellence Environm Safety & Biol Effects, Sch Environm & Energy Engn, Dept Chem & Chem Engn,Beijing Key Lab Green Catal, Beijing 100124, Peoples R China
  • [ 3 ] [XiLi, Dege]Beijing Univ Technol, Ctr Excellence Environm Safety & Biol Effects, Sch Environm & Energy Engn, Dept Chem & Chem Engn,Beijing Key Lab Green Catal, Beijing 100124, Peoples R China
  • [ 4 ] [Kang, Jing]Beijing Univ Technol, Ctr Excellence Environm Safety & Biol Effects, Sch Environm & Energy Engn, Dept Chem & Chem Engn,Beijing Key Lab Green Catal, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zhang, Lijuan]Beijing Univ Technol, Ctr Excellence Environm Safety & Biol Effects, Sch Environm & Energy Engn, Dept Chem & Chem Engn,Beijing Key Lab Green Catal, Beijing 100124, Peoples R China

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来源 :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

年份: 2020

卷: 341

6 . 6 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:33

JCR分区:2

被引次数:

WoS核心集被引频次: 36

SCOPUS被引频次: 39

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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