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Author:

Jiang, Yuyuan (Jiang, Yuyuan.) | Yan, Pengfei (Yan, Pengfei.) (Scholars:闫鹏飞) | Yu, Mingchao (Yu, Mingchao.) | Li, Jianming (Li, Jianming.) | Jiao, Hang (Jiao, Hang.) | Zhou, Bo (Zhou, Bo.) | Sui, Manling (Sui, Manling.)

Indexed by:

EI Scopus SCIE

Abstract:

Intergranular cracking at grain boundary is a well-known mechanical degradation for layered cathodes, which can trigger many detrimental consequences to degrade the cycling performance. To date, the atomistic mechanism of crack, especially the kinetic nucleation process, is still far from clear. Herein, we investigate the cracking mechanism at a coherent grain boundary, twin boundary in LiCoO2, by virtue of atomic resolution electron microscopy. Based on crack's nucleation and evolution process, two kinds of cracks are identified, the cleavage crack and the decomposition crack. The former is a typical deformation induced mechanical failure, featuring the electrochemomechanical fatigue degradation. The latter is formed due to thermodynamic decomposition, acting as the dominant cracking nucleation mechanism during high voltage cycling. Our work also demonstrates that twin boundary as an intrinsic planar defect energetically favors cracking, phase transformation and void formation, which stresses that stabilizing grain boundary mechanically and thermodynamically is vital towards high voltage usage of LiCoO2 and other layered cathodes for next generation lithium ion battery.

Keyword:

LiCoO2 Lithium-ion battery Cracking Twin boundary Phase transition

Author Community:

  • [ 1 ] [Jiang, Yuyuan]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 2 ] [Yan, Pengfei]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 3 ] [Yu, Mingchao]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 4 ] [Sui, Manling]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Jianming]Res Inst Petr Explorat & Dev, 20 Xueyuan Rd, Beijing, Peoples R China
  • [ 6 ] [Jiao, Hang]Res Inst Petr Explorat & Dev, 20 Xueyuan Rd, Beijing, Peoples R China
  • [ 7 ] [Zhou, Bo]Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China

Reprint Author's Address:

  • 闫鹏飞

    [Yan, Pengfei]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China;;[Sui, Manling]Beijing Univ Technol, Inst Microstruct & Properties Adv Mat, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China

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Source :

NANO ENERGY

ISSN: 2211-2855

Year: 2020

Volume: 78

1 7 . 6 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:169

Cited Count:

WoS CC Cited Count: 58

SCOPUS Cited Count: 62

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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