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作者:

Jin, Xiaodong (Jin, Xiaodong.) | Cui, Suping (Cui, Suping.) (学者:崔素萍) | Sun, Shibing (Sun, Shibing.) (学者:孙诗兵) | Gu, Xiaoyu (Gu, Xiaoyu.) | Li, Hongfei (Li, Hongfei.) | Sun, Jun (Sun, Jun.) | Zhang, Sheng (Zhang, Sheng.) | Bourbigot, Serge (Bourbigot, Serge.)

收录:

SCIE

摘要:

Owing to the biological compatibility and mechanical properties of polylactic acid (PLA), it presents an extensive application area (such as packaging, film, and fiber). However, the molten dripping phenomenon during combustion is still a drawback in the application of PLA. In this research, an intumescent flame retardant (A-A) was prepared based on the ionic exchange between p-aminobenzenesulfonic acid and ammonium polyphosphate. After that, A-A was molten compounded with PLA to improve its flame retardancy. It was suggested that the presence of 15% A-A could increase the limiting oxygen index value from 20.0% of neat PLA to 30.5%, enhance the UL results from none to V-0 and restrict the heat release during cone calorimeter test. Most importantly, the dripping behavior of PLA/15A-A composites while burning had been greatly minimized. On the basis of the mechanism analysis, it was suggested that A-A modified the initial degradation routine of PLA matrix, resulting to the rapid construction of protective barrier, thus endowing the antidripping property to the PLA/15A-A composites.

关键词:

antidripping flame retardant intumescent ionic exchange polylactic acid

作者机构:

  • [ 1 ] [Jin, Xiaodong]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Cui, Suping]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Sun, Shibing]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Jin, Xiaodong]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 5 ] [Gu, Xiaoyu]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 6 ] [Li, Hongfei]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 7 ] [Sun, Jun]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 8 ] [Zhang, Sheng]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 9 ] [Bourbigot, Serge]ENSCL ISP UMET, F-59652 Villeneuve Dascq, France

通讯作者信息:

  • 崔素萍

    [Cui, Suping]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China;;[Zhang, Sheng]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

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来源 :

ACS APPLIED POLYMER MATERIALS

ISSN: 2637-6105

年份: 2019

期: 4

卷: 1

页码: 755-764

5 . 0 0 0

JCR@2022

被引次数:

WoS核心集被引频次: 59

SCOPUS被引频次: 57

ESI高被引论文在榜: 0 展开所有

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