Electrochemically Oxidative Coupling of S-H/S-H for S-S Bond Formation: A Facile Approach to Diacid-disulfides - 文章详情页

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Scopus SCIE

摘要：

A　green　electrochemical　method　of　preparing　diacid-disulfides　has　been　developed,　in　which　an　S-S　bond　is　formed　by　electrochemically　oxidative　coupling　of　S-H/S-H　employing　redox　active　NaI　as　mediator.　The　reactions　are　carried　out　in　a　simple　undivided　cell　under　constant　current　condition　at　room　temperature　and　complete　in　1.3　h　to　afford　a　series　of　diacid-disulfides　with　up　to　97　%　yields.

关键词：

synthetic methods electrochemistry S-S bond formation halide ion as redox catalyst indirect electrolysis

作者机构：

[ 1 ] [Sun, Xue-Jie]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 2 ] [Yang, Shang-Feng]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 3 ] [Wang, Zhi-Tong]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 4 ] [Liang, Sen]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 5 ] [Tian, Hong-Yu]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 6 ] [Yang, Shao-Xiang]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 7 ] [Liu, Yong-Guo]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 8 ] [Sun, Bao-Guo]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 9 ] [Zeng, Cheng-Chu]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
[ 10 ] [Zeng, Cheng-Chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China

通讯作者信息：

[Liang, Sen]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China;;[Tian, Hong-Yu]Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China

电子邮件地址：

liangsen@btbu.edu.cn |
tianhy@btbu.edu.cn

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